Protection strategies for directionally-controlled synthesis of previously inaccessible metal-organic polyhedra (MOPs): the cases of carboxylate- and amino-functionalised Rh(ii)-MOPs

被引：39

作者：

Albalad, Jorge ^{[1
,2
]}

Carne-Sanchez, Arnau ^{[1
,2
]}

Grancha, Thais ^{[1
,2
]}

Hernandez-Lopez, Laura ^{[1
,2
]}

Maspoch, Daniel ^{[1
,2
,3
]}

机构：

[1] CSIC, Catalan Inst Nanosci & Nanotechnol ICN2, Campus UAB, Bellaterra 08193, Spain

[2] Barcelona Inst Sci & Technol, Campus UAB, Bellaterra 08193, Spain

[3] ICREA, Pg Lluis Co 23, Barcelona 08010, Spain

来源：

CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 85期

基金：

欧盟第七框架计划;

关键词：

SIDE REACTIONS; SUPPRESSION;

D O I：

10.1039/c9cc07083d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Herein we report that strategic use of protecting groups in coordination reactions enables directional inhibition that leads to synthesis of highly functionalised metal-organic polyhedra (MOPs), rather than of the extended coordination networks. Using this approach, we functionalised two new porous cuboctahedral Rh(ii)-based MOPs with 24 peripheral carboxylic acid groups or 24 peripheral amino groups.

引用

页码：12785 / 12788

页数：4

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