Esterification of octanoic acid using SiO2 doped sulfated aluminum-based solid acid as catalyst

被引：12

作者：

Duan, Yanan ^{[1
]}

Wu, Yulong ^{[1
,3
]}

Shi, Yanchun ^{[1
]}

Yang, Mingde ^{[1
]}

Zhang, Qinhui ^{[2
]}

Hu, Husheng ^{[1
]}

机构：

[1] Tsinghua Univ, Inst Nucl & New Energy Technol, Beijing 100084, Peoples R China

[2] China Univ Petr, State Key Lab Heavy Oil Proc, Jinan 266580, Shandong, Peoples R China

[3] Beijing Engn Res Ctr Biofuels, Beijing 100084, Peoples R China

来源：

CATALYSIS COMMUNICATIONS | 2016年 / 82卷

基金：

中国国家自然科学基金;

关键词：

Octanoic acid; Esterification; Sulfated aluminum-based solid acid; SiO2; promoter; ISOMERIZATION;

D O I：

10.1016/j.catcom.2016.04.013

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In this paper, SO42-/Al2O3-SiO2 (SAS) was prepared and used for the esterification of octanoic acid with methanol. The effect of introduction of SiO2 was characterized by nitrogen sorption, ICP-AES, XRD, NH3-TPD, TG, FFIR and FTIR-pyridine adsorption. The results demonstrated that the doping of SiO2 resulted in the increase of BET surface areas and amount of surface sulfur species which led to an increase of acid sites especially Bronsted acid sites, which consequently boosted the catalytic esterification activity. In addition, the introduction of SiO2 can also increase the thermal stability of SO4 and its interaction with Al2O3 support which resulted in the alleviation of catalyst deactivation. (C) 2016 Elsevier B.V. All rights reserved.

引用

页码：32 / 35

页数：4

共 24 条

[1]

Arata K., 1989, APPL CATAL A-GEN, V146, P3

[2]

Arata K. J. C. S., 1980, CHEM COMMUN, V2, P851

[3] Catalytic hydroconversion of tricaprylin and caprylic acid as model reaction for biofuel production from triglycerides [J].

Boda, Laszlo ;

Gyorgy Onyestyak ;

Solt, Hanna ;

Ferenc Lonyi ;

Valyon, Jozsef ;

Thernesz, Artrur .

APPLIED CATALYSIS A-GENERAL, 2010, 374 (1-2) :158-169

[4] Catalysis for conversion of biomass to fuels via pyrolysis and gasification: A review [J].

Bulushev, Dmitri A. ;

Ross, Julian R. H. .

CATALYSIS TODAY, 2011, 171 (01) :1-13

[5] Characteristics and properties of SiO2-Al2O3/EP-PU composite [J].

Chen Yu-fei ;

Dai Qi-wang ;

Lin Cai-wei ;

Feng Tao .

JOURNAL OF CENTRAL SOUTH UNIVERSITY, 2014, 21 (11) :4076-4083

[6] INORGANIC SOLID ACIDS AND THEIR USE IN ACID-CATALYZED HYDROCARBON REACTIONS [J].

CORMA, A .

CHEMICAL REVIEWS, 1995, 95 (03) :559-614

[7] Political, economic and environmental impacts of biofuels: A review [J].

Demirbas, Ayhan .

APPLIED ENERGY, 2009, 86 :S108-S117

[8] The Co-promotion effect of Mo and Nd on the activity and stability of sulfated zirconia-based solid acids in esterification [J].

Jiang, Kanghua ;

Tong, Dongmei ;

Tang, Jinqiang ;

Song, Ruili ;

Hu, Changwei .

APPLIED CATALYSIS A-GENERAL, 2010, 389 (1-2) :46-51

[9] Development of Pt/SO42-/ZrO2 catalyst for isomerization of light naphtha [J].

Kimura, T .

CATALYSIS TODAY, 2003, 81 (01) :57-63

[10] Transesterification of triacetin with methanol on solid acid and base catalysts [J].

López, DE ;

Goodwin, JG ;

Bruce, DA ;

Lotero, E .

APPLIED CATALYSIS A-GENERAL, 2005, 295 (02) :97-105

← 1 2 3 →