Room-Temperature Copper-Catalyzed Synthesis of Primary Arylamines from Aryl Halides and Aqueous Ammonia

被引：20
作者：
Tao, Chuanzhou [1 ]
Liu, Weiwei [1 ]
Lv, Aifeng [2 ]
Sun, Mingming [1 ]
Tian, Ying [1 ]
Wang, Qi [1 ]
Zhao, Jing [2 ]
机构：
[1] Huaihai Inst Technol, Sch Chem Engn, Lianyungang, Peoples R China
[2] Nanjing Univ, Sch Life Sci, State Key Lab Pharmaceut Biotechnol, Nanjing 210093, Peoples R China
来源：
SYNLETT | 2010年 / 09期
关键词：
copper; catalysis; cross-coupling; room temperature; aqueous ammonia; primary arylamine; BOND FORMATION; N-ARYLATION; NITROGEN LIGANDS; C-N; AMINATION; BROMIDES; ANILINES; AMINES; EQUIVALENTS; AMIDATION;
D O I：
10.1055/s-0029-1219922
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Primary arylamines can be prepared via a copper-catalyzed cross-coupling between aryl halides and aqueous ammonia using K3PO4 as a base and DMF as a solvent at room temperature.
引用
收藏
页码：1355 / 1358
页数：4
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