Selective recognition of m-dinitrobenzene based on NHC silver(I) macrometallocycle

被引：7

作者：

Liu, Qingxiang ^{[1
,2
]}

Sun, Xiaofeng ^{[1
,2
]}

Zhao, Dongxue ^{[1
,2
]}

Zhao, Zhixiang ^{[1
,2
]}

Liu, Rui ^{[1
,2
]}

Lv, Shizhen ^{[1
,2
]}

机构：

[1] Tianjin Normal Univ, Coll Chem, Minist Educ, Key Lab Inorgan Organ Hybrid Funct Mat Chem, Tianjin 300387, Peoples R China

[2] Tianjin Normal Univ, Coll Chem, Tianjin Key Lab Struct & Performance Funct Mol, Tianjin 300387, Peoples R China

来源：

SENSORS AND ACTUATORS B-CHEMICAL | 2017年 / 249卷

基金：

中国国家自然科学基金;

关键词：

N-heterocyclic carbene; Silver(I); Fluorescence recognition; m-Dinitrobenzene; METAL-ORGANIC FRAMEWORK; N-HETEROCYCLIC CARBENE; NITROAROMATIC EXPLOSIVES; CATALYTIC-ACTIVITY; MASS-SPECTROMETRY; NICKEL-COMPLEXES; LIGANDS; SENSITIVITY; MOLECULES; POLYMERS;

D O I：

10.1016/j.snb.2017.04.095

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The bis-imidazolium salt 1,4-bis[N-(9'-anthracenyl-methyl)imidazoliumyl]butane hexafluorophosphate ((LH2)-H-1 center dot(PF6)2) and its N-heterocyclic carbene (NHC) silver(I) macrometallocycle [((LAg)-Ag-1)(2)](PF6)(2) (1) have been prepared and characterized. 18-Membered macrometallocycle of 1 is formed via two ligands (L-1) and two silver(I) ions. The selective recognition of m-dinitrobenzene (DNB) using 1 as a host was studied on the basis of fluorescence titrations,H-1 NMRtitrations, HRMS spectra and IR spectra.The results indicate that 1 can distinguish effectively m-dinitrobenzene with other aromatic compounds. (C) 2017 Elsevier B.V. All rights reserved.

引用

页码：203 / 209

页数：7

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