Construction of Esters through Sulfuryl Fluoride (SO 2 F 2 ) Mediated Dehydrative Coupling of Carboxylic Acids with Alcohols at Room Temperature

被引：20
作者：
Wang, Shi-Meng [1 ,2 ]
Alharbi, Njud S. [3 ]
Qin, Hua-Li [1 ,2 ]
机构：
[1] Wuhan Univ Technol, State Key Lab Silicate Mat Architectures, 205 Luoshi Rd, Wuhan 430070, Hubei, Peoples R China
[2] Wuhan Univ Technol, Sch Chem Chem Engn & Life Sci, 205 Luoshi Rd, Wuhan 430070, Hubei, Peoples R China
[3] King Abdulaziz Univ, Fac Sci, Dept Biol Sci, Biotechnol Res Grp, Jeddah, Saudi Arabia
来源：
SYNTHESIS-STUTTGART | 2019年 / 51卷 / 20期
基金：
中国国家自然科学基金;
关键词：
esters; sulfuryl fluoride; dehydrative coupling; carboxylic acids; alcohols; CATALYZED OXIDATIVE ESTERIFICATION; CHEMOSELECTIVE ACYLATION; DIRECT CONVERSION; ARYL BROMIDES; PHENOLS; CARBONYLATION; FACILE; DERIVATIVES; ALDEHYDES; REAGENT;
D O I：
10.1055/s-0039-1690017
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A facile method for the construction of esters through dehydrative coupling of carboxylic acids with alcohols is developed. The reactions are mediated by sulfuryl fluoride (SO (2) F (2) ) at room temperature and proceed with high efficiency. The method has several advantages including broad substrate scope, mild conditions, excellent functional group compatibility and affords high yields, even on gram scale.
引用
收藏
页码：3901 / 3907
页数：7
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