Enantionselective enzymatic oxidation with indirect electrochemical NAD+ regeneration

被引：0
作者：
Schroeder, I [1 ]
Vasic-Racki, D [1 ]
Wandrey, C [1 ]
Liese, A [1 ]
机构：
[1] Forschungszentrum Julich, Res Ctr, Inst Biotechnol 2, D-52425 Julich, Germany
来源：
REACTIVE INTERMEDIATES IN ORGANIC AND BIOLOGICAL ELECTROCHEMISTRY | 2001年 / 2001卷 / 14期
关键词：
D O I：
暂无
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Glycerol dehydrogenase (GDH) [EC 1.1.1.6] from Cellulomonas species was used for oxidation of secondary alcohol functions. A test reaction system was established and characterized. 2,2'-Azino-bis(3-ethylbenzothiazoline-6-sulfonic acid) ABTS 1 was used as mediator for regeneration of nicotinamide-adenine-dinucleotide NAD(+) in its oxidized form. Kinetics were determined and based on the results a reactor system was proposed.
引用
收藏
页码：109 / 112
页数：4
相关论文
共 50 条
  • [21] HKUST-1 catalyzed efficient in situ regeneration of NAD+ for dehydrogenase mediated oxidation
    Xia, Huan
    Li, Zhixian
    Zhong, Xue
    Li, Binghui
    Jiang, Yunpeng
    Jiang, Yanbin
    CHEMICAL ENGINEERING SCIENCE, 2019, 203 : 43 - 53
  • [22] NAD+ -DEPENDENT OXIDATION OF ALDEHYDES IN DROSOPHILA
    GARCIN, F
    ALCOHOLISM-CLINICAL AND EXPERIMENTAL RESEARCH, 1982, 6 (02) : 296 - 296
  • [23] The influence of electrode material on NAD+ oxidation
    Saidman, SB
    Bessone, JB
    ELECTROCHIMICA ACTA, 2000, 45 (19) : 3151 - 3156
  • [24] NAD+ regeneration drives cancer cell proliferation
    Xu Han
    M. Celeste Simon
    Nature Metabolism, 2022, 4 : 647 - 648
  • [25] NAD+ regeneration drives cancer cell proliferation
    Han, Xu
    Simon, M. Celeste
    NATURE METABOLISM, 2022, 4 (06) : 647 - 648
  • [26] EFFICIENT PHOTOELECTROCHEMICAL INSITU REGENERATION OF NAD(P)+ COUPLED TO ENZYMATIC OXIDATION OF ALCOHOLS
    RUPPERT, R
    STECKHAN, E
    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1989, (07): : 811 - 814
  • [27] Enzymatic synthesis of NAD+ with the specific incorporation of atomic labels
    1600, (116):
  • [28] Electrochemical reduction of NAD+ on a polycrystalline gold electrode
    Damian, Alexis
    Omanovic, Sasha
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2006, 253 (1-2) : 222 - 233
  • [29] MACROMOLECULAR ENZYMATIC PRODUCT OF NAD+ IN LIVER-MITOCHONDRIA
    KUN, E
    ZIMBER, PH
    CHANG, ACY
    PUSCHENDORF, B
    GRUNICKE, H
    PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1975, 72 (04) : 1436 - 1440
  • [30] AN ENZYMATIC CYCLING PROCEDURE FOR NAD+ USING AN IRREVERSIBLE REACTION WITH NAD+-PEROXIDASE
    COX, C
    CAMUS, P
    BURET, J
    DUVIVIER, J
    ANALYTICAL BIOCHEMISTRY, 1982, 119 (01) : 185 - 193
12345