Enantionselective enzymatic oxidation with indirect electrochemical NAD+ regeneration

被引：0
|
作者：
Schroeder, I [1 ]
Vasic-Racki, D [1 ]
Wandrey, C [1 ]
Liese, A [1 ]
机构：
[1] Forschungszentrum Julich, Res Ctr, Inst Biotechnol 2, D-52425 Julich, Germany
来源：
REACTIVE INTERMEDIATES IN ORGANIC AND BIOLOGICAL ELECTROCHEMISTRY | 2001年 / 2001卷 / 14期
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D O I：
暂无
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Glycerol dehydrogenase (GDH) [EC 1.1.1.6] from Cellulomonas species was used for oxidation of secondary alcohol functions. A test reaction system was established and characterized. 2,2'-Azino-bis(3-ethylbenzothiazoline-6-sulfonic acid) ABTS 1 was used as mediator for regeneration of nicotinamide-adenine-dinucleotide NAD(+) in its oxidized form. Kinetics were determined and based on the results a reactor system was proposed.
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页码：109 / 112
页数：4
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