Friedel-Crafts alkylation of arenes with epoxides promoted by fluorinated alcohols or water

被引：111

作者：

Li, Guo-Xing ^{[1
]}

Qu, Jin ^{[1
]}

机构：

[1] Nankai Univ, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 15期

基金：

中国国家自然科学基金;

关键词：

CYCLIALKYLATIONS; CYCLIZATION; PHOTOLYSIS; OXIRANES; INDOLES; ENERGY; ARYL;

D O I：

10.1039/b926684d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The stereoselective intra- and intermolecular Friedel-Crafts alkylation of electron-rich arenes with epoxides can take place in refluxing 1,1,1,3,3,3-hexafluoroisopropanol owing to its weak acidity and high ionizing power.

引用

页码：2653 / 2655

页数：3

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