New source of evidence: Explosive traces in hair

被引:2
作者
Oxley, JC [1 ]
Smith, JL [1 ]
Kirschenbaum, L [1 ]
Shinde, KP [1 ]
Marimganti, S [1 ]
机构
[1] Univ Rhode Isl, Dept Chem, Kingston, RI 02881 USA
来源
SENSORS, AND COMMAND, CONTROL, COMMUNICATIONS, AND INTELLIGENCE(C31) TECHNOLOGIES FOR HOMELAND SECURITY AND HOMELAND DEFENSE III, PTS 1 AND 2 | 2004年 / 5403卷
关键词
TNT; RDX; PETN; TATP; hair; explosive sorption; explosive vapor;
D O I
10.1117/12.548165
中图分类号
TP39 [计算机的应用];
学科分类号
081203 ; 0835 ;
摘要
This study examines the sorption of explosives [TNT, RDX, PETN, TATP] to hair during exposure to their vapors. In each test, three colors of hair were simultaneously exposed to explosive vapor. Washing, extracting, and gas chromatographic quantification protocols were developed, and replication of quantitative data was confirmed. Results show that sorption of explosives, via vapor diffusion, to black hair is significantly greater than to blond, brown or bleached hair. Furthermore, the rate of sorption is directly related to the vapor density of the explosive: TATP >>> TNT >> PETN > RDX. Using TNT as the prototype, persistence of the explosive upon standing in air and upon repeated washing with sodium dodecyl sulfate was demonstrated. This study indicates that hair can be a useful indicator of explosive exposure/handling. Work is in progress to develop this technique into an effective forensic tool.
引用
收藏
页码:246 / 255
页数:10
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