Synthesis, crystal structure and electrochemical character of a novel mixed-ligand complex from ferrocene carboxylates

被引：0
作者：
Chen, QR [1 ]
Xu, H [1 ]
Hou, HW [1 ]
机构：
[1] Zhengzhou Univ, Dept Chem, Zhengzhou 450052, Peoples R China
来源：
CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2004年 / 20卷 / 10期
关键词：
ferrocene carboxylate; mixed-ligand complex; crystal structure; electrochemical character;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel mixed-ligand complex [Zn-2(L1)(2)(L2)(dpa)] (L1=3-ferrocenoylpropionic acid, L2=1,1'-ferrocenedipropionic acid, dpa=2,2'-dipyridylamine) has been synthesized by the reaction of Zn(Ac)(2).2H(2)O with L1, L2 and dpa and characterized by X-ray single crystal diffraction. The results reveal that it is a centrosymmetric binuclear complex. The hydrogen bonds N-H...O and C-H...0 connect [Zn-2(L1)(2)(L2)(dpa)] units into a supramolecular of 2-D structure. In addition, the electrochemical character of the complex was investigated by differential pulse volt-metric techniques.
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页码：1155 / 1158
页数：4
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