Hydrothermal Synthesis of Co3O4/ZnO Hybrid Nanoparticles for Triethylamine Detection

被引:64
作者
Yang, Yanqiong [1 ]
Wang, Xiaodong [1 ]
Yi, Guiyun [2 ]
Li, Huimin [1 ]
Shi, Chuang [1 ]
Sun, Guang [1 ]
Zhang, Zhanying [1 ]
机构
[1] Henan Polytech Univ, Sch Mat Sci & Engn, Jiaozuo 454000, Henan, Peoples R China
[2] Henan Polytech Univ, Coll Chem & Chem Engn, Jiaozuo 454000, Henan, Peoples R China
基金
中国国家自然科学基金;
关键词
Co3O4-ZnO; nanoparticles; hydrothermal; triethylamine detection; gas sensor; GAS-SENSING PROPERTIES; HOLLOW SPHERES; ORGANIC FRAMEWORKS; N HETEROJUNCTION; NANOSHEETS; SENSOR; PERFORMANCE; NANOROD; HETEROSTRUCTURES; CONSTRUCTION;
D O I
10.3390/nano9111599
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Development of high performances gas sensors to monitor and detect the volatile organic compound triethylamine is of paramount importance for health and environmental protection. The Co3O4-ZnO nanoparticles composite was successfully synthesized by the one-step hydrothermal route and annealing process in this work. The gas sensitivity test results show that the composite exhibits excellent triethylamine-sensing performance at a cobalt content of 1 at%, indicating potential application for triethylamine detection. The sensor based on the Co3O4-ZnO composite had higher sensitivity to triethylamine, better selectivity, and faster response recovery rate compared with pure ZnO sensor. Combined with the structural characteristics of the characterized Co3O4-ZnO nanocomposite, the optimized triethylamine sensing performances can be ascribed to the p-n heterojunction effect between Co3O4 and ZnO, as well as the catalytic and high oxygen adsorption properties of Co3O4.
引用
收藏
页数:12
相关论文
共 48 条
[31]   Construction of monodisperse vanadium pentoxide hollow spheres via a facile route and triethylamine sensing property [J].
Wu, Minzi ;
Zhang, Xianfa ;
Gao, Shan ;
Cheng, Xiaoli ;
Rong, Zimei ;
Xu, Yingming ;
Zhao, Hui ;
Huo, Lihua .
CRYSTENGCOMM, 2013, 15 (46) :10123-10131
[32]   ZIF-derived porous ZnO-Co3O4 hollow polyhedrons heterostructure with highly enhanced ethanol detection performance [J].
Xiong, Ya ;
Xu, Wangwang ;
Zhu, Zongye ;
Xue, Qingzhong ;
Lu, Wenbo ;
Ding, Degong ;
Zhu, Lei .
SENSORS AND ACTUATORS B-CHEMICAL, 2017, 253 :523-532
[33]   Superior triethylamine-sensing properties based on TiO2/SnO2 n-n heterojunction nanosheets directly grown on ceramic tubes [J].
Xu, Hongyan ;
Ju, Judianxing ;
Li, Wenru ;
Zhang, Jun ;
Wang, Jieqiang ;
Cao, Bingqiang .
SENSORS AND ACTUATORS B-CHEMICAL, 2016, 228 :634-642
[34]   The advances of Co3O4 as gas sensing materials: A review [J].
Xu, J. M. ;
Cheng, J. P. .
JOURNAL OF ALLOYS AND COMPOUNDS, 2016, 686 :753-768
[35]   Improved ethanol gas sensing performances of a ZnO/Co3O4 composite induced by its flytrap-like structure [J].
Xu, Keng ;
Yang, Li ;
Yang, Yong ;
Yuan, Cailei .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2017, 19 (43) :29601-29607
[36]   NiO@ZnO Heterostructured Nanotubes: Coelectrospinning Fabrication, Characterization, and Highly Enhanced Gas Sensing Properties [J].
Xu, Lin ;
Zheng, Ruifang ;
Liu, Shuhai ;
Song, Jian ;
Chen, Jiansheng ;
Dong, Biao ;
Song, Hongwei .
INORGANIC CHEMISTRY, 2012, 51 (14) :7733-7740
[37]   Hydrothermal Synthesis of CeO2-SnO2 Nanoflowers for Improving Triethylamine Gas Sensing Property [J].
Xue, Dongping ;
Wang, Yan ;
Cao, Jianliang ;
Zhang, Zhanying .
NANOMATERIALS, 2018, 8 (12)
[38]   novel sensor for fast detection of triethylamine based on rutile TiO2 nanorod arrays [J].
Yang, Hong-yan ;
Cheng, Xiao-Li ;
Zhang, Xian-Fa ;
Zheng, Zhi-kun ;
Tang, Xiao-fei ;
Xu, Ying-Ming ;
Gao, Shan ;
Zhao, Hui ;
Huo, Li-Hua .
SENSORS AND ACTUATORS B-CHEMICAL, 2014, 205 :322-328
[39]   Highly sensitive and selective triethylamine gas sensor based on porous SnO2/Zn2SnO4 composites [J].
Yang, Xueli ;
Yu, Qi ;
Zhang, Sufang ;
Sun, Peng ;
Lu, Huiying ;
Yan, Xu ;
Liu, Fangmeng ;
Zhou, Xin ;
Liang, Xishuang ;
Gao, Yuan ;
Lu, Geyu .
SENSORS AND ACTUATORS B-CHEMICAL, 2018, 266 :213-220
[40]   Fast triethylamine gas sensing response properties of nanosheets assembled WO3 hollow microspheres [J].
Zhai, Chengbo ;
Zhu, Mingming ;
Jiang, Lina ;
Yang, Tianye ;
Zhao, Qi ;
Luo, Yang ;
Zhang, Mingzhe .
APPLIED SURFACE SCIENCE, 2019, 463 :1078-1084