Hydrothermal Synthesis of Co3O4/ZnO Hybrid Nanoparticles for Triethylamine Detection

被引:64
作者
Yang, Yanqiong [1 ]
Wang, Xiaodong [1 ]
Yi, Guiyun [2 ]
Li, Huimin [1 ]
Shi, Chuang [1 ]
Sun, Guang [1 ]
Zhang, Zhanying [1 ]
机构
[1] Henan Polytech Univ, Sch Mat Sci & Engn, Jiaozuo 454000, Henan, Peoples R China
[2] Henan Polytech Univ, Coll Chem & Chem Engn, Jiaozuo 454000, Henan, Peoples R China
基金
中国国家自然科学基金;
关键词
Co3O4-ZnO; nanoparticles; hydrothermal; triethylamine detection; gas sensor; GAS-SENSING PROPERTIES; HOLLOW SPHERES; ORGANIC FRAMEWORKS; N HETEROJUNCTION; NANOSHEETS; SENSOR; PERFORMANCE; NANOROD; HETEROSTRUCTURES; CONSTRUCTION;
D O I
10.3390/nano9111599
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Development of high performances gas sensors to monitor and detect the volatile organic compound triethylamine is of paramount importance for health and environmental protection. The Co3O4-ZnO nanoparticles composite was successfully synthesized by the one-step hydrothermal route and annealing process in this work. The gas sensitivity test results show that the composite exhibits excellent triethylamine-sensing performance at a cobalt content of 1 at%, indicating potential application for triethylamine detection. The sensor based on the Co3O4-ZnO composite had higher sensitivity to triethylamine, better selectivity, and faster response recovery rate compared with pure ZnO sensor. Combined with the structural characteristics of the characterized Co3O4-ZnO nanocomposite, the optimized triethylamine sensing performances can be ascribed to the p-n heterojunction effect between Co3O4 and ZnO, as well as the catalytic and high oxygen adsorption properties of Co3O4.
引用
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页数:12
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