Characterizations of interpenetrating polymer network hydrogels composed of poly(vinyl alcohol) and poly(N-isopropylacrylamide)

被引：0
作者：
Kim, SJ [1 ]
Park, SJ [1 ]
Yoon, SG [1 ]
Lee, KJ [1 ]
Lee, YM [1 ]
Park, SB [1 ]
Kim, SI [1 ]
机构：
[1] Hanyang Univ, Dept Biomed Engn, Seoul 133791, South Korea
来源：
SMART MATERIALS II | 2002年 / 4934卷
关键词：
poly(vinyl alcohol); poly(N-isopropylacrylamide); water behavior;
D O I：
10.1117/12.469181
中图分类号：
TM [电工技术]; TN [电子技术、通信技术];
学科分类号：
0808 ; 0809 ;
摘要：
Interpenetrating polymer network (IPN) hydrogels based on poly(vinyl alcohol) (PVA) and poly(N-isopropylacrylamide) (PNIPAAm) were prepared by the sequential-IPN method. The IPN hydrogels were analyzed for sorption behavior of water at 35 degreesC and at a relative humidity (RE) of 95% using a dynamic vapor sorption system, and water diffusion coefficients were calculated. Differential scanning calorimetry (DSC) was used for the quantitative determination of the amounts of freezing and non-freezing water. Free water contents in the IPN hydrogel of IPN1, IPN2 and IPN3 were 45.8, 37.9 and 33.1% in pure water, respectively.
引用
收藏
页码：370 / 377
页数：8
相关论文
共 20 条
  • [1] [Anonymous], J APPL POLYM SCI
  • [2] Crank J., 1968, DIFFUSION POLYM
  • [3] INFLUENCE OF CO-POLYMER COMPOSITION ON NON-FICKIAN WATER TRANSPORT THROUGH GLASSY CO-POLYMERS
    FRANSON, NM
    PEPPAS, NA
    [J]. JOURNAL OF APPLIED POLYMER SCIENCE, 1983, 28 (04) : 1299 - 1310
  • [4] Water sorption studies of new pH-responsive N-acryloyl-N′-methyl piperazine and methyl methacrylate hydrogels
    Gan, LH
    Deen, GR
    Gan, YY
    Tam, KC
    [J]. EUROPEAN POLYMER JOURNAL, 2001, 37 (07) : 1473 - 1478
  • [5] PH-SENSITIVE MEMBRANES FROM POLY(VINYL ALCOHOL) POLY(ACRYLIC ACID) INTERPENETRATING NETWORKS
    GUDEMAN, LF
    PEPPAS, NA
    [J]. JOURNAL OF MEMBRANE SCIENCE, 1995, 107 (03) : 239 - 248
  • [6] Rapid deswelling response of poly(N-isopropylacrylamide) hydrogels by the formation of water release channels using poly(ethylene oxide) graft chains
    Kaneko, Y
    Nakamura, S
    Sakai, K
    Aoyagi, T
    Kikuchi, A
    Sakurai, Y
    Okano, T
    [J]. MACROMOLECULES, 1998, 31 (18) : 6099 - 6105
  • [7] INFLUENCE OF FREELY MOBILE GRAFTED CHAIN-LENGTH ON DYNAMIC PROPERTIES OF COMB-TYPE GRAFTED POLY(N-ISOPROPYLACRYLAMIDE) HYDROGELS
    KANEKO, Y
    SAKAI, K
    KIKUCHI, A
    YOSHIDA, R
    SAKURAI, Y
    OKANO, T
    [J]. MACROMOLECULES, 1995, 28 (23) : 7717 - 7723
  • [8] Kim SY, 1999, J APPL POLYM SCI, V74, P1752, DOI 10.1002/(SICI)1097-4628(19991114)74:7<1752::AID-APP18>3.3.CO
  • [9] 2-8
  • [10] Kim SY, 1999, J APPL POLYM SCI, V73, P1675, DOI 10.1002/(SICI)1097-4628(19990829)73:9<1675::AID-APP8>3.0.CO
12