Application of reactive cyclodextrin poly butyl acrylate preformed polymers containing nano-ZnO to cotton fabrics and their impact on fabric performance

被引:24
作者
El Shafei, Amira [1 ]
Shaarawy, S. [1 ]
Hebeish, A. [1 ]
机构
[1] Natl Res Ctr, Text Res Div, Cairo 00202, Egypt
关键词
Textile finishing; Nanoparticles; Cyclodextrin; Anti-microbial; Air permeability;
D O I
10.1016/j.carbpol.2009.10.007
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Synthesis of reactive preformed polymers (PFP) and their application to cotton fabrics along with epichlorohydrin and/or ZnO nanoparticles are carried out as per the conventional pad-dry-cure method. PFP refers to monochlorotrazinyl beta-cycloclextrin grafted with Butyl acrylate. The impact of grafting of this reactive preformed polymer on performance of cotton fabrics was studied. These grafting of PFP to cotton fabrics in presence of ZnO nanoparticles and /or epichlorohydrin imparts antibacterial activity which withstands 20 times washing while keeping 70% of this activity. These grafted fabrics acquire improved air permeability indicating better breathability and comfortability of garments make thereof. Also reported was the characterization of the grafted fabrics using IR spectral analysis and scanning electron microscopy. A ZnO nanoparticle was also characterized using UV-vis spectrophotometer. (C) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码:852 / 857
页数:6
相关论文
共 23 条
[1]   The curious world of polypseudorotaxanes: Cyclodextrins as probes of water structure [J].
Becheri, A ;
Lo Nostro, P ;
Ninham, BW ;
Baglioni, P .
JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (16) :3979-3987
[2]  
Belosludov R, 2002, SP S CLUST PHYS, P109
[3]   Nanoparticles derived from amphiphilic γ-cyclodextrins [J].
Cavalli, Roberta ;
Trotta, Francesco ;
Carlotti, M. Eugenia ;
Possetti, Barbara ;
Trotta, Michele .
JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, 2007, 57 (1-4) :657-661
[4]   Cyclodextrins and their uses: a review [J].
Del Valle, EMM .
PROCESS BIOCHEMISTRY, 2004, 39 (09) :1033-1046
[5]   Rigidity versus flexibility. A review of experimental and theoretical studies pertaining to the cyclodextrin nonrigidity [J].
Dodziuk, H .
JOURNAL OF MOLECULAR STRUCTURE, 2002, 614 (1-3) :33-45
[6]   Nanosilver functionalized cotton fabric [J].
Gorensek, Marija ;
Recetj, Petra .
TEXTILE RESEARCH JOURNAL, 2007, 77 (03) :138-141
[7]   A SURVEY OF ANTIFUNGAL COMPOUNDS FROM HIGHER-PLANTS, 1982-1993 [J].
GRAYER, RJ ;
HARBORNE, JB .
PHYTOCHEMISTRY, 1994, 37 (01) :19-42
[8]   Synthesis and Characterization of Multifunctional Cotton Containing Cyclodextrin and Butylacrylate Moieties [J].
Hebeish, A. ;
El Shafei, A. ;
Shaarawy, S. .
POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING, 2009, 48 (08) :839-850
[9]   Formation of a flame retardant-cyclodextrin inclusion compound and its application as a flame retardant for poly(ethylene terephthalate) [J].
Huang, L ;
Gerber, M ;
Lu, J ;
Tonelli, AE .
POLYMER DEGRADATION AND STABILITY, 2001, 71 (02) :279-284
[10]  
IROB ON, 1996, INT J PHARMACEUT, V34, P84