Synthesis and crystal structure of nickel complex of N,N-bis(benzimidazol-2-yl-methyl)amine

被引：16

作者：

Xu, JY ^{[1
]}

Gu, W ^{[1
]}

Li, L ^{[1
]}

Yan, SP ^{[1
]}

Cheng, P ^{[1
]}

Liao, DZ ^{[1
]}

Jiang, ZH ^{[1
]}

机构：

[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2003年 / 644卷 / 1-3期

基金：

中国国家自然科学基金;

关键词：

crystal structure; N; N-bis(benzimidazol-2-yl-methyl)aniine; nickel(II) complex; hydrogen bond;

D O I：

10.1016/S0022-2860(02)00281-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A new nickel(II) complex, [NiL2]Cl-2 (L = N,N-bis(benzimidazol-2-yl-methyl)amine), was synthesized and its crystal structure was determined. According to X-ray crystallographic studies, each nickel(II) ion was six-coordinated with six nitrogen atoms of two L ligands. The complex crystallizes in triclinic system, space group P (1) over bar, a = 9.764(3) Angstrom, b = 11.032(3) Angstrom, c = 16.402(5) Angstrom, alpha = 80.529(6)degrees, beta = 79.180(7)degrees, gamma = 74.232(6)degrees, and Z = 2. The title complex forms two-dimensional hydrogen bond network structures between the chlorine atoms and the nitrogens of L. The IR and UV spectroscopy were measured. The absorption bands of d-d electron transition are assigned, the values of Dq and B were calculated according to the electronic spectrum of the complex. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：23 / 27

页数：5

共 10 条

[1] CRYSTALLIZATION AND PRELIMINARY-X-RAY ANALYSIS OF THE SUPEROXIDE-DISMUTASE FROM MYCOBACTERIUM-TUBERCULOSIS [J].