Visible-Light Promoted Catalyst-Free Imidation of Arenes and Heteroarenes

被引：125

作者：

Song, Lu ^{[1
]}

Zhang, Long ^{[1
]}

Luo, Sanzhong ^{[1
,2
]}

Cheng, Jin-Pei ^{[1
]}

机构：

[1] Chinese Acad Sci Beijing, BNLMS, CAS Key Lab Mol Recognit & Funct, Inst Chem, Beijing 100190, Peoples R China

[2] Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300071, Peoples R China

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2014年 / 20卷 / 44期

关键词：

CH imidation; N-bromosaccharin; photolysis; visible-light; C-H AMINATION; N BOND FORMATION; INTERMOLECULAR AMINATION; IMIDYL RADICALS; TRIFLUOROMETHYLATION; AMIDATION; ROUTE; MILD; FUNCTIONALIZATION; PHTHALIMIDATION;

D O I：

10.1002/chem.201404479

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We described herein a catalyst-free visible-light photolytic protocol for the imidation of arenes and heteroarenes. N-Bromosaccharin was identified as a viable and chemoselective nitrogen radical precursor that undergoes controllable homolytic cleavage under ambient light irradiation. The reaction can be applied to a number of arenes and heteroarenes with good chemo- and regioselectivity. Mechanistic studies revealed that radical chain termination by electron transfer-proton transfer (ET-PT) is the leading productive pathway for the reaction.

引用

页码：14231 / 14234

页数：4

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