Crystal structure of 2,6-diphenyl-3-methyl-N-nitrosopiperidin-4-one

被引：5

作者：

Hemalatha, T. ^{[1
]}

Nagarajan, S. ^{[1
]}

机构：

[1] Annamalai Univ, Dept Chem, Annamalainagar 608002, Tamil Nadu, India

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2010年 / 963卷 / 2-3期

关键词：

Piperidone; N-Nitrosopiperidone; Conformations; Crystal structure; MAGNETIC RESONANCE; STEREODYNAMICS; CONFIGURATIONS; SHIFTS;

D O I：

10.1016/j.molstruc.2009.10.021

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The structure of the 2,6-diphenyl-3-methyl-N-nitrosopiperidin-4-one (C18H18N2O2) has been investigated in solution and in the solid state by IR, NMR and X-ray methods. The crystal belongs to the monoclinic space group P21/n with a = 7.7134(6), b = 14.7754(14), c = 27.321(3) angstrom and beta = 94.617(3)degrees. In crystal structure, the piperidine ring adopts a boat conformation with a slight distortion. One of the phenyl groups is in axial orientation, while the other phenyl and methyl groups are in equatorial orientations. (c) 2009 Elsevier B.V. All rights reserved.

引用

页码：111 / 114

页数：4

共 22 条

[1] TABLES OF BOND LENGTHS DETERMINED BY X-RAY AND NEUTRON-DIFFRACTION .1. BOND LENGTHS IN ORGANIC-COMPOUNDS
ALLEN, FH
KENNARD, O
WATSON, DG
BRAMMER, L
ORPEN, AG
TAYLOR, R
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1987, (12): : S1 - S19
[2] POLYMORPHISM OF FREE 2,2,6,6 TETRAMETHYL PIPERIDINONE-4 OXYL-1 NITROXIDE RADICLE - REFINED ORTHORHOMBIC STRUCTURE
BORDEAUX, D
LAJZEROWICZ, J
[J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS, 1974, 30 (MAR15): : 790 - 792
[3] DECAMP WH, 1974, CRYST STRUCT COMMUN, V3, P427
[4] CANCER AND CHEMICALS
FERGUSON, LN
[J]. CHEMICAL SOCIETY REVIEWS, 1975, 4 (02) : 289 - 322
[5] Synthesis, antibacterial and antifungal activities of some N-nitroso-2,6-diarylpiperidin-4-one semicarbazones and QSAR analysis
Hemalatha, T.
Imran, P. K. M.
Gnanamani, A.
Nagarajan, S.
[J]. NITRIC OXIDE-BIOLOGY AND CHEMISTRY, 2008, 19 (04): : 303 - 311
[6] HOFER O, 1976, TOP STEREOCHEM, pP9
[7] STRUCTURE OF 3,5-BIS(BENZYLIDENE)-1-METHYL-4-PIPERIDONE METHOBROMIDE HEMIETHANOL SOLVATE
JIA, ZC
QUAIL, JW
ARORA, VK
DIMMOCK, JR
[J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1989, 45 : 1117 - 1118
[8] STRUCTURAL STUDIES BY NUCLEAR MAGNETIC RESONANCE .9. CONFIGURATIONS + CONFORMATIONS OF N-NITROSAMINES
KARABATSOS, GJ
TALLER, RA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1964, 86 (20) : 4373 - &
[9] NITROSO TRANSFER FROM ALPHA-NITROSAMINO ALDEHYDES - IMPLICATIONS FOR CARCINOGENESIS
LOEPPKY, RN
TOMASIK, W
KERRICK, BE
[J]. CARCINOGENESIS, 1987, 8 (07) : 941 - 946
[10] LOONEY CE, 1957, J AM CHEM SOC, V79, P6163

← 1 2 3 →