New magnetoactive copper complexes with Schiff's bases

被引:18
作者
Burlov, A. S.
Koshchienko, Yu. V.
Ikorskii, V. N.
Vlasenko, V. G.
Zarubin, I. A.
Uraev, A. I.
Vasil'chenko, I. S.
Garnovskii, D. A.
Borodkin, G. S.
Nikolaevskii, S. A.
Garnovskii, A. D.
机构
[1] Rostov State Univ, S Sci Ctr, Russian Acad Sci, Res Inst Phys & Organ Chem, Rostov Na Donu 344104, Russia
[2] Russian Acad Sci, Siberian Div, Int Tomog Ctr, Novosibirsk 630090, Russia
[3] Rostov State Univ, Inst Phys Res, Rostov Na Donu 344104, Russia
基金
俄罗斯基础研究基金会;
关键词
D O I
10.1134/S0036023606070096
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Tridentate azomethine ligands with N2O and N-3 donor atoms and their copper complexes have been synthesized and characterized. Magnetochemical measurements in the temperature range of 5-300 K show that the change in the coordination environment induces the change in the sign of exchange coupling in the molecules of complexes.
引用
收藏
页码:1065 / 1070
页数:6
相关论文
共 40 条
  • [1] Snapshots of dioxygen activation by copper:: The structure of a 1:1 Cu/O2 adduct and its use in syntheses of asymmetric bis(μ-oxo) complexes
    Aboelella, NW
    Lewis, EA
    Reynolds, AM
    Brennessel, WW
    Cramer, CJ
    Tolman, WB
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (36) : 10660 - 10661
  • [2] Synthesis and structural and magnetic characterization of discrete phenolate and imidazolate bridged Gd(III)-M(II) [M = Cu, Ni] dinuclear complexes
    Brewer, C
    Brewer, G
    Scheidt, WR
    Shang, MY
    Carpenter, EE
    [J]. INORGANICA CHIMICA ACTA, 2001, 313 (1-2) : 65 - 70
  • [3] New layered polymeric metamagnet based on copper(II) complex with 3-imidazoline nitroxide
    Burdukov, A
    Shvedenkov, Y
    Pervukhina, N
    Reznikov, V
    [J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2005, (09) : 1776 - 1780
  • [4] CHERNOVA NI, 1971, ZH ORG KHIM+, V7, P1680
  • [5] Is ferromagnetism an intrinsic property of the CuII/GdIII couple?: 1.: Structures and magnetic properties of two novel dinuclear complexes with a μ-phenolato-μ-oximato (Cu,Gd) core
    Costes, JP
    Dahan, F
    Dupuis, A
    Laurent, JP
    [J]. INORGANIC CHEMISTRY, 2000, 39 (02) : 169 - 173
  • [6] COSTES JP, 2003, J CHEM SOC DA, P464
  • [7] FOSTER R, 1957, J CHEM SOC, P4687
  • [8] Garner CR, 2005, ARS COMBINATORIA, V74, P3
  • [9] Garnovskii A.D., 2003, Synthetic Coordination and Organometallic Chemistry
  • [10] Garnovskii A.D., 2002, Russ. Chem. Rev., V71, P943, DOI [DOI 10.1070/RC2002V071N11ABEH000759, 10.1070/RC2002v071n11ABEH000759]