The 2022 solar fuels roadmap

被引：88

作者：

Segev, Gideon ^{[1
]}

Kibsgaard, Jakob ^{[2
]}

Hahn, Christopher ^{[3
]}

Xu, Zhichuan J. ^{[4
]}

Cheng, Wen-Hui ^{[5
]}

Deutsch, Todd G. ^{[6
]}

Xiang, Chengxiang ^{[7
]}

Zhang, Jenny Z. ^{[8
]}

Hammarstrom, Leif ^{[9
]}

Nocera, Daniel G. ^{[10
]}

Weber, Adam Z. ^{[11
]}

Agbo, Peter ^{[12
]}

Hisatomi, Takashi ^{[13
,14
]}

Osterloh, Frank E. ^{[15
]}

Domen, Kazunari ^{[13
,16
]}

Abdi, Fatwa F. ^{[17
]}

Haussener, Sophia ^{[18
]}

Miller, Daniel J. ^{[12
]}

Ardo, Shane ^{[19
]}

McIntyre, Paul C. ^{[20
]}

Hannappel, Thomas ^{[21
]}

Hu, Shu ^{[22
]}

Atwater, Harry ^{[23
]}

Gregoire, John M. ^{[24
]}

Ertem, Mehmed Z. ^{[25
,26
]}

Sharp, Ian D. ^{[27
,28
]}

Choi, Kyoung-Shin ^{[29
]}

Lee, Jae Sung ^{[30
]}

Ishitani, Osamu ^{[31
]}

Ager, Joel W. ^{[32
,33
]}

Prabhakar, Rajiv Ramanujam ^{[12
]}

Bell, Alexis T. ^{[12
,34
]}

Boettcher, Shannon W. ^{[35
,36
]}

Vincent, Kylie ^{[37
]}

Takanabe, Kazuhiro ^{[38
]}

Artero, Vincent ^{[39
]}

Napier, Ryan ^{[40
]}

Roldan Cuenya, Beatriz ^{[41
]}

Koper, Marc T. M. ^{[40
]}

Van de Krol, Roel ^{[17
,42
]}

Houle, Frances ^{[12
]}

机构：

[1] Tel Aviv Univ, Fac Engn, Dept Phys Elect, Tel Aviv, Israel

[2] Tech Univ Denmark, Dept Phys, DK-2800 Lyngby, Denmark

[3] Lawrence Livermore Natl Lab, Mat Sci Div, Livermore, CA 94550 USA

[4] Nanyang Technol Univ, Sch Mat Sci & Engn, Singapore, Singapore

[5] Natl Cheng Kung Univ, Dept Mat Sci & Technol, Tainan 701, Taiwan

[6] Natl Renewable Energy Lab, 15013 Denver West Pkwy, Golden, CO 80401 USA

[7] CALTECH, Dept Appl Phys & Mat Sci, Pasadena, CA 91125 USA

[8] Univ Cambridge, Yusuf Hamied Dept Chem, Lensfield Rd, Cambridge CB2 1EW, England

[9] Uppsala Univ, Dept Chem, Angstrom Labs, Box 523, SE-75120 Uppsala, Sweden

[10] Harvard Univ, Dept Chem & Chem Biol, 12 Oxford St, Cambridge, MA 02138 USA

[11] Lawrence Berkeley Natl Lab, Energy Technol Area, Energy Convers Grp, Berkeley, CA 94720 USA

[12] Lawrence Berkeley Natl Lab, Chem Sci Div, Berkeley, CA 94720 USA

[13] Shinshu Univ, Interdisciplinary Cluster Cutting Edge Res, Res Initiat Supra Mat, 4-17-1 Wakasato, Nagano, Nagano 3808553, Japan

[14] JST PRESTO, 4-17-1 Wakasato, Nagano, Nagano 3808553, Japan

[15] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA

[16] Univ Tokyo, Off Univ Prof, Bunkyo Ku, 2-11-16 Yayoi, Tokyo 1138656, Japan

[17] Helmholtz Zentrum Berlin Mat & Energie GmbH, Inst Solar Fuels, Hahn Meitner Pl 1, D-14109 Berlin, Germany

[18] Ecole Polytech Fed Lausanne EPFL, Lab Renewable Energy Sci & Engn, Stn 9, CH-1015 Lausanne, Switzerland

[19] Univ Calif Irvine, Dept Chem, Dept Chem & Biomol Engn, Dept Mat Sci & Engn, Irvine, CA 92697 USA

[20] Stanford Univ, Dept Mat Sci & Engn, Stanford, CA 94305 USA

[21] Tech Univ Ilmenau, Inst Phys, Fundamentals Energy Mat, D-98693 Ilmenau, Thuringia, Germany

[22] Yale Univ, Dept Chem & Environm Engn, New Haven, CT 06520 USA

[23] CALTECH, Thomas J Watson Lab Appl Phys, Pasadena, CA 91125 USA

[24] CALTECH, Div Engn & Appl Sci, Pasadena, CA 91024 USA

[25] CALTECH, Liquid Sunlight Alliance, Pasadena, CA 91024 USA

[26] Brookhaven Natl Lab, Chem Div, Upton, NY 11973 USA

[27] Tech Univ Munich, Walter Schottky Inst, D-85748 Garching, Germany

[28] Tech Univ Munich, Phys Dept, D-85748 Garching, Germany

[29] Univ Wisconsin, Dept Chem, Madison, WI 53706 USA

[30] Ulsan Natl Inst Sci & Technol UNIST, Sch Energy & Chem Engn, Dept Energy Engn, Ulsan 44919, South Korea

[31] Tokyo Inst Technol, Dept Chem, Meguro Ku, 2-12-1-NE-1 Ookayama, Tokyo, Japan

[32] Lawrence Berkeley Natl Lab, Mat Sci Div, Berkeley, CA 94720 USA

[33] Univ Calif Berkeley, Dept Mat Sci & Engn, Berkeley, CA 94720 USA

[34] Univ Calif Berkeley, Dept Chem & Biomol Engn, Berkeley, CA 94720 USA

[35] Univ Oregon, Dept Chem & Biochem, Eugene, OR 97403 USA

[36] Univ Oregon, Oregon Ctr Electrochem, Eugene, OR 97403 USA

[37] Univ Oxford, Dept Chem, Inorgan Chem Lab, South Parks Rd, Oxford OX1 3QR, England

[38] Univ Tokyo, Sch Engn, Dept Chem Syst Engn, Bunkyo Ku, 7-3-1 Hongo, Tokyo 1138656, Japan

[39] Univ Grenoble Alpes, Lab Chim & Biol Metaux, IRIG, CNRS,CEA, 17 Rue Martyrs, F-38054 Grenoble, France

[40] Leiden Univ, Leiden Inst Chem, POB 9502, NL-2300 RA Leiden, Netherlands

[41] Max Planck Gesell, Dept Interface Sci, Fritz Haber Inst, Faradayweg 4-6, D-14195 Berlin, Germany

[42] Tech Univ Berlin, Inst Chem, Str 17 Juni 124, D-10623 Berlin, Germany

来源：

JOURNAL OF PHYSICS D-APPLIED PHYSICS | 2022年 / 55卷 / 32期

基金：

瑞士国家科学基金会; 日本科学技术振兴机构; 英国生物技术与生命科学研究理事会; 日本学术振兴会; 新加坡国家研究基金会; 荷兰研究理事会; 欧洲研究理事会; 美国国家科学基金会; 欧盟地平线“2020”;

关键词：

solar fuels; catalysis; CO2; reduction; water splitting; ELECTROCHEMICAL CO2 REDUCTION; CARBON-DIOXIDE REDUCTION; MONOLITHIC PHOTOELECTROCHEMICAL DEVICE; WATER-SPLITTING ACTIVITY; HYDROGEN-PRODUCTION; ELECTROCATALYTIC CONVERSION; ARTIFICIAL PHOTOSYNTHESIS; PHOTOCATALYTIC REDUCTION; PHOTOCHEMICAL REDUCTION; COORDINATION POLYMER;

D O I：

10.1088/1361-6463/ac6f97

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

Renewable fuel generation is essential for a low carbon footprint economy. Thus, over the last five decades, a significant effort has been dedicated towards increasing the performance of solar fuels generating devices. Specifically, the solar to hydrogen efficiency of photoelectrochemical cells has progressed steadily towards its fundamental limit, and the faradaic efficiency towards valuable products in CO2 reduction systems has increased dramatically. However, there are still numerous scientific and engineering challenges that must be overcame in order to turn solar fuels into a viable technology. At the electrode and device level, the conversion efficiency, stability and products selectivity must be increased significantly. Meanwhile, these performance metrics must be maintained when scaling up devices and systems while maintaining an acceptable cost and carbon footprint. This roadmap surveys different aspects of this endeavor: system benchmarking, device scaling, various approaches for photoelectrodes design, materials discovery, and catalysis. Each of the sections in the roadmap focuses on a single topic, discussing the state of the art, the key challenges and advancements required to meet them. The roadmap can be used as a guide for researchers and funding agencies highlighting the most pressing needs of the field.

引用

页数：52

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