Highly sensitive electrochemical sensor for tulobuterol detection based on facile graphene/Au nanowires modified glassy carbon electrode

被引:12
作者
Huang, Huayu [1 ]
Nie, Rong [2 ]
Song, Yanyan [3 ]
Ji, Yongsheng [4 ]
Guo, Rui [3 ]
Liu, Zhihua [1 ]
机构
[1] Northwest Univ, Coll Urban & Environm Sci, Xian 710127, Peoples R China
[2] Gansu Prov Ctr Dis Control & Prevent, Lanzhou 730000, Peoples R China
[3] Shaanxi Univ Sci & Technol, Sch Chem & Chem Engn, Xian 710021, Peoples R China
[4] Henan Univ Tradit Chinese Med, Coll Pharm, Zhengzhou 450000, Peoples R China
关键词
Graphene; Au nanowire; Electrochemical sensor; Tulobuterol; TANDEM MASS-SPECTROMETRY; LIQUID-CHROMATOGRAPHY; GOLD NANOPARTICLE; SHEETS;
D O I
10.1016/j.snb.2016.02.099
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Graphene/Au nanowire (G/Au NW) composites were prepared facilely by mixing well-dispersed graphene and Au nanowires and used to modify the glassy carbon electrodes as a tulobuterol electrochemical sensor. The modification activity of the composites was investigated with the electrochemical impedance spectroscopy technique. A sensitive, rapid and simple electrochemical method was developed for the detection of tulobuterol based on the strong enhancement effect of G/Au NWs. The peak currents varied linearly with the concentration of tulobuterol over the range from 7.6 x 10(-8) to 7.6 x 10(-8) mol L-1, and the detection limit was 1.36;: 10(-8) mol L-1 (SIN=3). The electrode developed can be used for the electroanalytical detection of tulobuterol and provide a potential application of tulobuterol in further research. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:422 / 426
页数:5
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