A lithium anode protection guided highly-stable lithium-sulfur battery

被引：356
作者：
Ma, Guoqiang [1 ]
Wen, Zhaoyin [1 ]
Wu, Meifen [1 ]
Shen, Chen [1 ]
Wang, Qingsong [1 ]
Jin, Jun [1 ]
Wu, Xiangwei [1 ]
机构：
[1] Chinese Acad Sci, Shanghai Inst Ceram, CAS Key Lab Mat Energy Convers, Shanghai 200050, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 91期
关键词：
HIGH-PRESSURE; CATHODE; COMPOSITE; LI3N; PERFORMANCE; GRAPHENE; LI/S;
D O I：
10.1039/c4cc05535g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A Li3N protection layer is fabricated on the surface of a Li anode by an in situ method to suppress the shuttle effect on the basis of anode protection. The discharge capacity is retained at 773 mA h g(-1) after 500 cycles with an average coulombic efficiency of 92.3% in the electrolyte without LiNO3, while the sulfur loading of the simple sulfur cathode was 2.5-3 mg cm(-2).
引用
收藏
页码：14209 / 14212
页数：4
相关论文
共 31 条
  • [1] IONIC-CONDUCTIVITY IN LI3N SINGLE-CRYSTALS
    ALPEN, UV
    RABENAU, A
    TALAT, GH
    [J]. APPLIED PHYSICS LETTERS, 1977, 30 (12) : 621 - 623
  • [2] On the Surface Chemical Aspects of Very High Energy Density, Rechargeable Li-Sulfur Batteries
    Aurbach, Doron
    Pollak, Elad
    Elazari, Ran
    Salitra, Gregory
    Kelley, C. Scordilis
    Affinito, John
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2009, 156 (08) : A694 - A702
  • [3] Chang YC, 2004, J CHIN INST CHEM ENG, V35, P425
  • [4] Sulfur-Impregnated, Sandwich-Type, Hybrid Carbon Nanosheets with Hierarchical Porous Structure for High-Performance Lithium-Sulfur Batteries
    Chen, Xi'an
    Xiao, Zhubing
    Ning, Xutao
    Liu, Zheng
    Yang, Zhi
    Zou, Chao
    Wang, Shun
    Chen, Xiaohua
    Chen, Ying
    Huang, Shaoming
    [J]. ADVANCED ENERGY MATERIALS, 2014, 4 (13)
  • [5] Structural transition of Li3N under high pressure: A first-principles study
    Cui, Shouxin
    Feng, Wenxia
    Hu, Haiquan
    Feng, Zhenbao
    Wang, Yuanxu
    [J]. SOLID STATE COMMUNICATIONS, 2009, 149 (15-16) : 612 - 615
  • [6] Li-S batteries: simple approaches for superior performance
    Demir-Cakan, Rezan
    Morcrette, Mathieu
    Gangulibabu
    Gueguen, Aurelie
    Dedryvere, Remi
    Tarascon, Jean-Marie
    [J]. ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (01) : 176 - 182
  • [7] Analysis of the Sulfur Cathode Capacity Fading Mechanism and Review of the Latest Development for Li-S Battery
    Diao Yan
    Xie Kai
    Hong Xiaobin
    Xiong Shizhao
    [J]. ACTA CHIMICA SINICA, 2013, 71 (04) : 508 - 518
  • [8] Li-B Alloy as Anode Material for Lithium/Sulfur Battery
    Duan, Bochao
    Wang, Weikun
    Zhao, Hailei
    Wang, Anbang
    Wang, Mengjia
    Yuan, Keguo
    Yu, Zhongbao
    Yang, Yusheng
    [J]. ECS ELECTROCHEMISTRY LETTERS, 2013, 2 (06) : A47 - A51
  • [9] Electrical Energy Storage for the Grid: A Battery of Choices
    Dunn, Bruce
    Kamath, Haresh
    Tarascon, Jean-Marie
    [J]. SCIENCE, 2011, 334 (6058) : 928 - 935
  • [10] New Approaches for High Energy Density Lithium-Sulfur Battery Cathodes
    Evers, Scott
    Nazar, Linda F.
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 2013, 46 (05) : 1135 - 1143
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