Recent advances in the synthesis of hierarchically porous silica materials on the basis of porous glasses

被引:37
作者
Inayat, Alexandra [1 ]
Reinhardt, Bjorn [2 ]
Herwig, Jan [2 ]
Kuester, Christian [2 ]
Uhlig, Hans [3 ]
Krenkel, Sharon [4 ]
Raedlein, Edda [4 ]
Enke, Dirk [2 ]
机构
[1] Univ Erlangen Nurnberg, Inst Chem React Engn, Egerlandstr 3, D-91058 Erlangen, Germany
[2] Univ Leipzig, Inst Chem Technol, Linneestr 3-4, D-04103 Leipzig, Germany
[3] Univ Leipzig, Inst Nichtklass Chem, Permoserstr 15, D-04318 Leipzig, Germany
[4] Tech Univ Ilmenau, Dept Inorgan Nonmetall Materials, Gustav Kirchoffstr 6, D-98693 Ilmenau, Germany
关键词
MFI-TYPE; HYDROTHERMAL TRANSFORMATION; MONOLITHS; MCM-41; MANUFACTURE; CARBONS; BEADS;
D O I
10.1039/c5nj03591k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The thermal phase separation and subsequent leaching of sodium borosilicate glasses is a well established route for the preparation of porous glasses exhibiting adjustable pore sizes in the range of 1 nm up to almost 1 mu m as well as a very flexible geometric shape. The combination of this route with a large spectrum of synthesis strategies for the implementation of an additional pore system enables the preparation of hierarchically porous glass-based materials. This review covers a wide range of preparative routes for hierarchically porous silica materials starting from the sodium borosilicate glass with a special emphasis on the very recent developments in this versatile field of materials engineering.
引用
收藏
页码:4095 / 4114
页数:20
相关论文
共 55 条
[41]   Hydrothermal transformation of porous glass granules into ZSM-5 granules [J].
Rauscher, M ;
Selvam, T ;
Schwieger, W ;
Freude, D .
MICROPOROUS AND MESOPOROUS MATERIALS, 2004, 75 (03) :195-202
[42]  
Reinhardt B., 2014, THESIS U LEIPZIG
[43]   Hierarchically structured glass monoliths based on polyurethane foams as template [J].
Reinhardt, Bjoern ;
Herwig, Jan ;
Rannabauer, Stefan ;
Scheffler, Michael ;
Enke, Dirk .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2014, 34 (05) :1465-1470
[44]   Preparation of Porous, Hierarchically Organized Glass Monoliths via Combination of Sintering and Phase Separation [J].
Reinhardt, Bjoern ;
Enke, Dirk ;
Syrowatka, Frank .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2012, 95 (02) :461-465
[45]   Transformation of porous glass beads into MFI-type containing beads [J].
Scheffler, F ;
Schwieger, W ;
Freude, D ;
Liu, H ;
Heyer, W ;
Janowski, F .
MICROPOROUS AND MESOPOROUS MATERIALS, 2002, 55 (02) :181-191
[46]  
Scheffler M, 2005, CELLULAR CERAMICS: STRUCTURE, MANUFACTURING, PROPERTIES AND APPLICATIONS, P1, DOI 10.1002/3527606696
[47]  
Schwartzwalder K., 1963, United States patent, Patent No. [3090094A, 3090094, 3,090,094]
[48]   Hierarchy concepts: classification and preparation strategies for zeolite containing materials with hierarchical porosity [J].
Schwieger, Wilhelm ;
Machoke, Albert Gonche ;
Weissenberger, Tobias ;
Inayat, Amer ;
Selvam, Thangaraj ;
Klumpp, Michael ;
Inayat, Alexandra .
CHEMICAL SOCIETY REVIEWS, 2016, 45 (12) :3353-3376
[49]  
Selvam T, 2004, STUD SURF SCI CATAL, V154, P598
[50]  
SIEBERS FB, 1989, GLASTECH BER-GLASS, V62, P63