Recent advances in the synthesis of hierarchically porous silica materials on the basis of porous glasses

被引:37
作者
Inayat, Alexandra [1 ]
Reinhardt, Bjorn [2 ]
Herwig, Jan [2 ]
Kuester, Christian [2 ]
Uhlig, Hans [3 ]
Krenkel, Sharon [4 ]
Raedlein, Edda [4 ]
Enke, Dirk [2 ]
机构
[1] Univ Erlangen Nurnberg, Inst Chem React Engn, Egerlandstr 3, D-91058 Erlangen, Germany
[2] Univ Leipzig, Inst Chem Technol, Linneestr 3-4, D-04103 Leipzig, Germany
[3] Univ Leipzig, Inst Nichtklass Chem, Permoserstr 15, D-04318 Leipzig, Germany
[4] Tech Univ Ilmenau, Dept Inorgan Nonmetall Materials, Gustav Kirchoffstr 6, D-98693 Ilmenau, Germany
关键词
MFI-TYPE; HYDROTHERMAL TRANSFORMATION; MONOLITHS; MCM-41; MANUFACTURE; CARBONS; BEADS;
D O I
10.1039/c5nj03591k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The thermal phase separation and subsequent leaching of sodium borosilicate glasses is a well established route for the preparation of porous glasses exhibiting adjustable pore sizes in the range of 1 nm up to almost 1 mu m as well as a very flexible geometric shape. The combination of this route with a large spectrum of synthesis strategies for the implementation of an additional pore system enables the preparation of hierarchically porous glass-based materials. This review covers a wide range of preparative routes for hierarchically porous silica materials starting from the sodium borosilicate glass with a special emphasis on the very recent developments in this versatile field of materials engineering.
引用
收藏
页码:4095 / 4114
页数:20
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