Strain-induced crystallization in sustainably crosslinked epoxidized natural rubber

被引：28
|
作者：
Imbernon, L. [1 ]
Pauchet, R. [1 ]
Pire, M. [1 ]
Albouy, P. -A. [2 ]
Tence-Girault, S. [1 ]
Norvez, S. [1 ]
机构：
[1] PSL Res Univ, UMR 7167, CNRS, Matiere Molle & Chim,ESPCI ParisTech, 10 Rue Vauquelin, F-75005 Paris, France
[2] Univ Paris 11, UMR 8502, CNRS, Lab Phys Solides, F-91405 Orsay, France
来源：
POLYMER | 2016年 / 93卷
关键词：
Strain-induced crystallization; Epoxidized natural rubber; Sustainable; DICARBOXYLIC-ACIDS; NETWORK; LINKING; ORIENTATION; EPOXIDATION; BLENDS; IR; NR;
D O I：
10.1016/j.polymer.2016.04.023
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Strain-induced crystallization (SIC) is studied in networks of epoxidized natural rubber crosslinked with eco-friendly dodecanedioic acid, by X-ray scattering measurements during cyclic stretching. An orientation parameter is calculated to quantitatively describe the behaviour of the amorphous phase during loading and unloading. Comparison with sulphur-vulcanized rubbers shows that SIC lattice parameters are independent of the nature of the crosslinks, and that unexpectedly the crosslink density affects the onset of crystallization. The revealed SIC behaviour is associated with the good mechanical properties of this sustainable rubber. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码：189 / 197
页数：9
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