Phototriggered supramolecular polymerization of a [c2] daisy chain rotaxane

被引：30
|
作者：
Fu, Xin
Gu, Rui-Rui
Zhang, Qi
Rao, Si-Jia
Zheng, Xiu-Li
Qu, Da-Hui [1 ]
Tian, He
机构：
[1] E China Univ Sci & Technol, Key Lab Adv Mat, 130 Meilong Rd, Shanghai 200237, Peoples R China
来源：
POLYMER CHEMISTRY | 2016年 / 7卷 / 12期
关键词：
FLUORESCENT ORGANIC NANOPARTICLES; REVERSIBLE CONVERSION; POLYMERS; DRIVEN; COMBINATION; MONOMERS;
D O I：
10.1039/c6py00309e
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A new strategy for phototriggered supramolecular polymerization of the [c2] daisy chain is demonstrated. A daisy chain rotaxane containing two coumarin protected 2-ureido-4-pyrimidinone (Upy) terminals at two ends was designed, whose supramolecular polymerization can be initiated by light irradiation that can remove the photocleavable protecting coumarin groups and uncage the two terminal Upy functional units.
引用
收藏
页码：2166 / 2170
页数：5
相关论文
共 50 条
  • [41] Bistable [c2] Daisy Chain Rotaxanes as Reversible Muscle-like Actuators in Mechanically Active Gels
    Goujon, Antoine
    Lang, Thomas
    Mariani, Giacomo
    Moulin, Emilie
    Fuks, Gad
    Raya, Jesus
    Buhler, Eric
    Giuseppone, Nicolas
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (42) : 14825 - 14828
  • [42] Maximizing the [c2]daisy chain to lasso ratio through competitive self-templating clipping reactions
    Saura-Sanmartin, Adrian
    Pastor, Aurelia
    Martinez-Cuezva, Alberto
    Berna, Jose
    CHEMICAL COMMUNICATIONS, 2021, 58 (02) : 290 - 293
  • [43] Computational prediction of optimal metal ions to induce coordinated polymerization of muscle-like [c2]daisy chains
    Zhao, Yan-Ling
    Zhang, Rui-Qin
    Minot, Christian
    Hermann, Klaus
    Van Hove, Michel A.
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2016, 18 (10) : 7419 - 7426
  • [44] Dynamic covalent templated-synthesis of [c2] daisy chains
    Bozdemir, O. Altan
    Barin, Gokhan
    Belowich, Matthew E.
    Basuray, Ashish N.
    Beuerle, Florian
    Stoddart, J. Fraser
    CHEMICAL COMMUNICATIONS, 2012, 48 (84) : 10401 - 10403
  • [45] Pillar[5]arene-neutral guest recognition based supramolecular alternating copolymer containing [c2] daisy chain and bis-pillar[5]arene units
    Wang, Xiaoyang
    Han, Kang
    Li, Jian
    Jia, Xueshun
    Li, Chunju
    POLYMER CHEMISTRY, 2013, 4 (14) : 3998 - 4003
  • [46] Revealing highly unbalanced energy barriers in the extension and contraction of the muscle-like motion of a [c2]daisy chain
    Zhao, Yan-Ling
    Zhang, Rui-Qin
    Minot, Christian
    Hermann, Klaus
    Van Hove, Michel A.
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2015, 17 (28) : 18318 - 18326
  • [47] Self-sorting of crown ether/secondary ammonium ion hetero-[c2]daisy chain pseudorotaxanes
    Zheng, Bo
    Klautzsch, Fabian
    Xue, Min
    Huang, Feihe
    Schalley, Christoph A.
    ORGANIC CHEMISTRY FRONTIERS, 2014, 1 (05): : 532 - 540
  • [48] Ditopic pillar[5]arene-based fluorescence enhancement material mediated by [c2]daisy chain formation
    Wang, Kai
    Wang, Chun-Yu
    Zhang, Yumo
    Zhang, Sean Xiao-An
    Yang, Bing
    Yang, Ying-Wei
    CHEMICAL COMMUNICATIONS, 2014, 50 (67) : 9458 - 9461
  • [49] ORGN 372-Toward molecular muscles: [c2]Daisy-chain dimer synthesis and incorporation into materials
    Clark, Paul G.
    Grubbs, R. H.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2009, 237
  • [50] A [2]rotaxane capped by a cyclodextrin and a guest: Formation of supramolecular [2]rotaxane polymer
    Miyauchi, M
    Hoshino, T
    Yamaguchi, H
    Kamitori, S
    Harada, A
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (07) : 2034 - 2035
12345