Crystal structure of a novel phenolato, azido, and acetato co-bridged trinuclear zinc(II) complex derived from 4-chloro-2-[(2-diethylaminoethylimino)methyl]phenol

被引：4
作者：
Sheng, G. -H. [1 ]
Cheng, X. -S. [2 ]
You, Z. -L. [2 ]
Zhu, H. -L. [1 ]
机构：
[1] Shandong Univ Technol, Sch Life Sci, Zibo, Shandong, Peoples R China
[2] Liaoning Normal Univ, Dept Chem & Chem Engn, Dalian, Peoples R China
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2014年 / 55卷 / 06期
关键词：
Schiff base; trinuclear complex; zinc complex; crystal structure; X-ray crystallography; COPPER(II);
D O I：
10.1134/S002247661406016X
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel phenolato, azido, and acetato co-bridged trinuclear zinc(II) complex [Zn3L2(mu(2)-CH3COO)(2) (mu(1,1)-N-3)(N-3)], where L is the deprotonated form of 4-chloro-2-[(2-diethylaminoethylimino)methyl]phenol, is prepared and characterized by elemental analysis, infrared spectrum, and single crystal X-ray determination. The complex crystallizes in the triclinic space group , with unit cell dimensions a = 12.7196(5) , b = 13.6597(6) , c = 13.7214(5) , alpha = 65.700(1)A degrees, beta = 83.429(1)A degrees, gamma = 63.545(1)A degrees, V = 1938.4(1) (3), Z = 2, GOOF = 1.013, R (1) = 0.0456, and wR (2) = 0.1032. Structural analysis shows that the distances among the adjacent zinc atoms are 3.282(1) and 3.213(1) . The zinc atoms are in distorted square pyramidal and trigonal bipyramidal coordinations.
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页码：1106 / 1110
页数：5
相关论文
共 18 条
[1]   Optical sensitization and upconversion in discrete polynuclear chromium-lanthanide complexes [J].
Aboshyan-Sorgho, Lilit ;
Cantuel, Martine ;
Petoud, Stephane ;
Hauser, Andreas ;
Piguet, Claude .
COORDINATION CHEMISTRY REVIEWS, 2012, 256 (15-16) :1644-1663
[2]   SYNTHESIS, STRUCTURE, AND SPECTROSCOPIC PROPERTIES OF COPPER(II) COMPOUNDS CONTAINING NITROGEN SULFUR DONOR LIGANDS - THE CRYSTAL AND MOLECULAR-STRUCTURE OF AQUA[1,7-BIS(N-METHYLBENZIMIDAZOL-2'-YL)-2,6-DITHIAHEPTANE]COPPER(II) PERCHLORATE [J].
ADDISON, AW ;
RAO, TN ;
REEDIJK, J ;
VANRIJN, J ;
VERSCHOOR, GC .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1984, (07) :1349-1356
[3]  
[Anonymous], 2015, Acta Crystallogr., V71, P3
[4]  
[Anonymous], 2002, BRUK SMART SAINT
[5]   A Rare Phenoxido/Acetato/Azido Bridged Trinuclear and an Unprecedented Phenoxido/Azido Bridged One-Dimensional Polynuclear Nickel(II) Complexes: Synthesis, Crystal Structure, and Magnetic Properties with Theoretical Investigations on the Exchange Mechanism [J].
Biswas, Rituparna ;
Mukherjee, Sandip ;
Kar, Paramita ;
Ghosh, Ashutosh .
INORGANIC CHEMISTRY, 2012, 51 (15) :8150-8160
[6]   Preparation, characterization and thermogravimetric studies of (N,N′-cis-1,2-cyclohexylene bis(salicylideneaminato)]cobalt(II) and [N,N′-(±)-trans-1,2-cyclohexylene bis(salicylideneaminato)]cobalt(II) [J].
Felicio, RC ;
Cavalheiro, ETG ;
Dockal, ER .
POLYHEDRON, 2001, 20 (3-4) :261-268
[7]   Factors Dictating the Nuclearity/Aggregation and Acetate Coordination Modes of Lutidine-Coordinated Zinc(II) Acetate Complexes [J].
Kumar, Umesh ;
Thomas, Jency ;
Thirupathi, Natesan .
INORGANIC CHEMISTRY, 2010, 49 (01) :62-72
[8]   Dinuclear zinc(II) complexes with compartmental ligands: syntheses, structures, and bioactivities as artificial nuclease [J].
Maiti, Pali ;
Khan, Amitava ;
Chattopadhyay, Tanmay ;
Das, Sudhanshu ;
Manna, Krishnendu ;
Bose, Dipayan ;
Dey, Sanjit ;
Zangrando, Ennio ;
Das, Debasis .
JOURNAL OF COORDINATION CHEMISTRY, 2011, 64 (21) :3817-3831
[9]   Polynuclear croconato-bridged-copper(II) complexes derived from tri- and tetra-dentate amines [J].
Massoud, Salah S. ;
Vicente, Ramon ;
Fontenot, Patricia R. ;
Gallo, August A. ;
Mikuriya, Masahiro ;
Albering, Joerg H. ;
Mautner, Franz A. .
POLYHEDRON, 2012, 46 (01) :66-73
[10]   Synthesis and structure determination of two new dinuclear end-to-end doubly bridged azido- and thiocyanato-copper(II) complexes derived from diethyldiethylenetriamine [J].
Massoud, SS ;
Mautner, FA .
INORGANICA CHIMICA ACTA, 2005, 358 (12) :3334-3340
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