An Aromatic Glaser-Hay Reaction

被引：148
|
作者：
Do, Hien-Quang [1 ]
Daugulis, Olafs [1 ]
机构：
[1] Univ Houston, Dept Chem, Houston, TX 77204 USA
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 47期
关键词：
COPPER-CATALYZED ARYLATION; C-H; DIRECTED ZINCATION; GRIGNARD-REAGENTS; BOND FORMATION; ARYL; FUNCTIONALIZATION; ALKENYLATION; ARENES; OXYGEN;
D O I：
10.1021/ja907479j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A general method for copper-catalyzed deprotonative dimerization of arenes by employing oxygen as the terminal oxidant has been developed. Electron-rich and electron-poor heterocycles as well as electron-poor arenes are reactive. The method is tolerant to functionalities such as nitro, cyano, dialkylamino, and ester groups.
引用
收藏
页码：17052 / +
页数：3
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