An Aromatic Glaser-Hay Reaction

被引：148

作者：

Do, Hien-Quang ^{[1
]}

Daugulis, Olafs ^{[1
]}

机构：

[1] Univ Houston, Dept Chem, Houston, TX 77204 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 47期

关键词：

COPPER-CATALYZED ARYLATION; C-H; DIRECTED ZINCATION; GRIGNARD-REAGENTS; BOND FORMATION; ARYL; FUNCTIONALIZATION; ALKENYLATION; ARENES; OXYGEN;

D O I：

10.1021/ja907479j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A general method for copper-catalyzed deprotonative dimerization of arenes by employing oxygen as the terminal oxidant has been developed. Electron-rich and electron-poor heterocycles as well as electron-poor arenes are reactive. The method is tolerant to functionalities such as nitro, cyano, dialkylamino, and ester groups.

引用

页码：17052 / +

页数：3

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