New macrocyclic oligoboronates

被引：57

作者：

Hopfl, H ^{[1
]}

Farfan, N ^{[1
]}

机构：

[1] Inst Politecn Nacl, Ctr Invest & Estudios Avanzados, Dept Quim, Mexico City 07000, DF, Mexico

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1997年 / 547卷 / 01期

关键词：

macrocyclic boron complexes; self-assembly; host-guest;

D O I：

10.1016/S0022-328X(97)00183-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new macrocyclic oligoboronates were prepared in easy one step syntheses from aminodialcohols and phenylboronic acid. Reaction of 2,6-pyridinedimethanol gives a tetrameric species, while 2-(salicylideneamino)-1-hydroxyethane provides a cyclobisboronate. Both compounds are characterized by using X-ray structural analyses. Possible applications in the supramolecular host-guest chemistry an discussed. (C) 1997 Elsevier Science S.A.

引用

页码：71 / 77

页数：7

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