Transformations of stereoisomeric 2-chloro-3-R-pentane-1,5-diones in reaction with phenylhydrazine

被引:2
作者
Moskovkina, T. V. [1 ]
Kalinovskii, A. I.
机构
[1] Far Eastern State Univ, Vladivostok 690600, Russia
[2] Russian Acad Sci, Pacific Inst Bioorgan Chem, Far Eastern Div, Vladivostok, Russia
关键词
D O I
10.1134/S1070428007020108
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Monophenylhydrazones were prepared from three monochloro derivatives of arylaliphatic 1,5-diketones, and some their transformations were investigated. The monophenyihydrazones formed regiospecifically, and the direction of the reaction was governed by the substituent attached to C-3 atom in the initial chlorodiketones. C Formerly unknown products of transformations suffered by monophenylhydrazones obtained were described: 2-amino-1,3-diphenyl-3-(2-phenylindolyl-3)-propan-1-one, 3-benzoyl-2,4,6-triphenl-2,3,4,5-tetrahydropyridazine, and 3-methyl-1,5-diphenyl-5-phenylazopent-4-en-1-one.
引用
收藏
页码:214 / 219
页数:6
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