Synthesis of dimethylformamide from CO2, H2 and dimethylamine over Cu/ZnO

被引：63

作者：

Liu, Jinli ^{[1
]}

Guo, Chengkun ^{[1
]}

Zhang, Zhaofu ^{[1
]}

Jiang, Tao ^{[1
]}

Liu, Huizhen ^{[1
]}

Song, Jinliang ^{[1
]}

Fan, Honglei ^{[1
]}

Han, Buxing ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 31期

基金：

中国国家自然科学基金;

关键词：

SUPERCRITICAL CARBON-DIOXIDE; METHANOL SYNTHESIS; HOMOGENEOUS HYDROGENATION; IONIC LIQUID; FORMIC-ACID; ZINC-OXIDE; CATALYSTS; MORPHOLOGY; EPOXIDES; FORMATE;

D O I：

10.1039/c0cc00751j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cheap and simple Cu/ZnO catalysts are very effective and recyclable for the synthesis of dimethylformamide (DMF) from CO2, H-2, and dimethylamine, and a yield of 97% can be reached.

引用

页码：5770 / 5772

页数：3

共 31 条

[11] Homogeneous catalysis in supercritical fluids: Hydrogenation of supercritical carbon dioxide to formic acid, alkyl formates, and formamides [J].

Jessop, PG ;

Hsiao, Y ;

Ikariya, T ;

Noyori, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (02) :344-355

[12] Migration and reduction of formate to form methanol on Cu/ZnO catalysts [J].

Joo, OS ;

Jung, KD ;

Han, SH ;

Uhm, SJ ;

Lee, DK ;

Ihm, SK .

APPLIED CATALYSIS A-GENERAL, 1996, 135 (02) :273-286

[13] Redox-transmetalation process as a generalized synthetic strategy for core-shell magnetic nanoparticles [J].

Lee, WR ;

Kim, MG ;

Choi, JR ;

Park, JI ;

Ko, SJ ;

Oh, SJ ;

Cheon, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (46) :16090-16097

[14] CARBON-DIOXIDE AS A RAW-MATERIAL - THE SYNTHESIS OF FORMIC-ACID AND ITS DERIVATIVES FROM CO2 [J].

LEITNER, W .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1995, 34 (20) :2207-2221

[15] Thirteen-week inhalation toxicity of N,N-dimethylformamide in F344/N rats and B6C3F1 mice [J].

Lynch, DW ;

Placke, ME ;

Persing, RL ;

Ryan, MJ .

TOXICOLOGICAL SCIENCES, 2003, 72 (02) :347-358

[16] On the issue of the active site and the role of ZnO in Cu/ZnO methanol synthesis catalysts [J].

Nakamura, J ;

Choi, Y ;

Fujitani, T .

TOPICS IN CATALYSIS, 2003, 22 (3-4) :277-285

[17] Aspects of carbon dioxide utilization [J].

Omae, Iwao .

CATALYSIS TODAY, 2006, 115 (1-4) :33-52

[18] Kinetic implications of dynamical changes in catalyst morphology during methanol synthesis over Cu/ZnO catalysts [J].

Ovesen, CV ;

Clausen, BS ;

Schiotz, J ;

Stoltze, P ;

Topsoe, H ;

Norskov, JK .

JOURNAL OF CATALYSIS, 1997, 168 (02) :133-142

[19] Catalytic activation of CO2: Use of secondary CO2 for the production of synthesis gas and for methanol synthesis over copper-based zirconia-containing catalysts [J].

Raudaskoski, R. ;

Turpeinen, E. ;

Lenkkeri, R. ;

Pongracz, E. ;

Keiski, R. L. .

CATALYSIS TODAY, 2009, 144 (3-4) :318-323

[20] LIVER-DISEASE ASSOCIATED WITH OCCUPATIONAL EXPOSURE TO THE SOLVENT DIMETHYLFORMAMIDE [J].

REDLICH, CA ;

BECKETT, WS ;

SPARER, J ;

BARWICK, KW ;

RIELY, CA ;

MILLER, H ;

SIGAL, SL ;

SHALAT, SL ;

CULLEN, MR .

ANNALS OF INTERNAL MEDICINE, 1988, 108 (05) :680-686

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