Synthesis of dimethylformamide from CO2, H2 and dimethylamine over Cu/ZnO

被引:63
作者
Liu, Jinli [1 ]
Guo, Chengkun [1 ]
Zhang, Zhaofu [1 ]
Jiang, Tao [1 ]
Liu, Huizhen [1 ]
Song, Jinliang [1 ]
Fan, Honglei [1 ]
Han, Buxing [1 ]
机构
[1] Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China
基金
中国国家自然科学基金;
关键词
SUPERCRITICAL CARBON-DIOXIDE; METHANOL SYNTHESIS; HOMOGENEOUS HYDROGENATION; IONIC LIQUID; FORMIC-ACID; ZINC-OXIDE; CATALYSTS; MORPHOLOGY; EPOXIDES; FORMATE;
D O I
10.1039/c0cc00751j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Cheap and simple Cu/ZnO catalysts are very effective and recyclable for the synthesis of dimethylformamide (DMF) from CO2, H-2, and dimethylamine, and a yield of 97% can be reached.
引用
收藏
页码:5770 / 5772
页数:3
相关论文
共 31 条
[1]   Meso- and nano-structuring of industrial Cu/ZnO/(Al2O3) catalysts [J].
Behrens, Malte .
JOURNAL OF CATALYSIS, 2009, 267 (01) :24-29
[2]   MECHANISM AND KINETICS OF METHANOL SYNTHESIS ON ZINC-OXIDE [J].
BOWKER, M ;
HOUGHTON, H ;
WAUGH, KC .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1981, 77 :3023-3036
[3]   CRYSTAL PLANE DEPENDENCE OF ADSORPTION AND REACTION ON ZINC-OXIDE [J].
BOWKER, M ;
HOUGHTON, H ;
WAUGH, KC ;
GIDDINGS, T ;
GREEN, M .
JOURNAL OF CATALYSIS, 1983, 84 (01) :252-255
[4]   Making plastics from carbon dioxide:: Salen metal complexes as catalysts for the production of polycarbonates from epoxides and CO2 [J].
Darensbourg, Donald J. .
CHEMICAL REVIEWS, 2007, 107 (06) :2388-2410
[5]   The hydrogenation of carbon dioxide and a correction of the reported synthesis of urethans [J].
Farlow, MW ;
Adkins, H .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1935, 57 :2222-2223
[6]  
Haynes P., 1970, Tetrahedron Lett, V11, P365
[7]  
IMAI T, 1981, Patent No. 4269998
[8]   Recent advances in the homogeneous hydrogenation of carbon dioxide [J].
Jessop, PG ;
Joó, F ;
Tai, CC .
COORDINATION CHEMISTRY REVIEWS, 2004, 248 (21-24) :2425-2442
[9]   CATALYTIC PRODUCTION OF DIMETHYLFORMAMIDE FROM SUPERCRITICAL CARBON-DIOXIDE [J].
JESSOP, PG ;
HSIAO, Y ;
IKARIYA, T ;
NOYORI, R .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (19) :8851-8852
[10]   HOMOGENEOUS HYDROGENATION OF CARBON-DIOXIDE [J].
JESSOP, PG ;
IKARIYA, T ;
NOYORI, R .
CHEMICAL REVIEWS, 1995, 95 (02) :259-272