Sustainable Cyclic Carbonate Production, Utilizing Carbon Dioxide and Azolate Ionic Liquids

被引：90

作者：

Goodrich, Peter ^{[1
]}

Gunaratne, H. Q. Nimal ^{[1
]}

Jacquemin, Johan ^{[1
]}

Jin, Lili ^{[1
,2
]}

Lei, Yuntao ^{[1
,2
]}

Seddon, Kenneth R. ^{[1
]}

机构：

[1] Queens Univ Belfast, Sch Chem & Chem Engn, QUILL Res Ctr, Stranmillis Rd, Belfast BT9 5AG, Antrim, North Ireland

[2] China Pharmaceut Univ, Sch Sci, 639 Longmian Rd, Nanjing 210009, Jiangsu, Peoples R China

来源：

ACS SUSTAINABLE CHEMISTRY & ENGINEERING | 2017年 / 5卷 / 07期

关键词：

Green chemistry; Azolate ionic liquids; Recyclable catalysts; Epoxides; Cyclic carbonates; N-HETEROCYCLIC CARBENES; CO2; FIXATION; EFFICIENT CATALYST; CHEMICAL FIXATION; COUPLING REACTION; OXALYL CHLORIDE; EPOXIDES; CYCLOADDITION; TRANSFORMATION; TEMPERATURE;

D O I：

10.1021/acssuschemeng.7b00355

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An efficient protocol is described for producing cyclic carbonates in good to excellent yields under moderate reaction conditions (100.0 degrees C, 1.0 MPa) by treating epoxides with carbon dioxide, promoted by a series of azolate ionic liquids, which are effective, recyclable, metal-free, and halide-free catalysts.

引用

页码：5635 / 5641

页数：7

共 62 条

[61] Task-specific ionic liquid and CO2-cocatalysed efficient hydration of propargylic alcohols to α-hydroxy ketones [J].