Is Pt/C More Electrocatalytic than Ru/C for Hydrogen Evolution in Alkaline Electrolytes?

被引：25
|
作者：
Shao, Ru-Yang [1 ]
Chen, Lin-Wei [1 ]
Yan, Qiang-Qiang [1 ]
Zeng, Wei-Jie [1 ]
Yin, Peng [1 ]
Liang, Hai-Wei [1 ]
机构：
[1] Univ Sci & Technol China, Dept Chem, Div Nanomat & Chem, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Anhui, Peoples R China
来源：
ACS APPLIED ENERGY MATERIALS | 2021年 / 4卷 / 05期
基金：
中国国家自然科学基金;
关键词：
ruthenium; benchmark catalyst; hydrogen evolution; catalyst; Pt/C; OXIDATION; PLATINUM; PH; ACID; NANOPARTICLES; CATALYSTS; MECHANISM; HOR/HER;
D O I：
10.1021/acsaem.1c00308
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
It has been widely accepted that Pt is more electrocatalytic than Ru for alkaline hydrogen evolution reactions (HERs), probably on the basis of the previous studies on bulk metals. Herein, we report that, in strong contrast with the previously reported results on bulk metals, the nanoparticular Ru supported on carbon (Ru/C) exhibits much higher alkaline HER performance than Pt supported on carbon (Pt/C). We further demonstrate that both commercial and homemade Ru/C catalysts are even more active than most reported Ru-based materials. These results suggest that Ru/C should be used as benchmark material instead of Pt/C for evaluating the alkaline HER performance of catalysts.
引用
收藏
页码：4284 / 4289
页数：6
相关论文
共 50 条
  • [1] Tuning the oxidation state of Ru to surpass Pt in hydrogen evolution reaction
    Ma, Rongpeng
    Wang, Ying
    Li, Guoqiang
    Yang, Long
    Liu, Shiwei
    Jin, Zhao
    Zhao, Xiao
    Ge, Junjie
    Xing, Wei
    NANO RESEARCH, 2021, 14 (11) : 4321 - 4327
  • [2] On the Origins of Intrinsic Limitations of Electrocatalytic Hydrogen Evolution in Alkaline Media
    Zeradjanin, Aleksandar R.
    Narangoda, Praveen
    Masa, Justus
    CHEMCATCHEM, 2024, 16 (18)
  • [3] Gas Flow Sputtering of Pt/C Films and their Performance in Electrocatalytic Hydrogen Evolution Reaction
    Bernsmeier, Denis
    Selve, Soeren
    Nissen, Joerg
    Maticiuc, Natalia
    Ibaceta-Jana, Josefa
    Szyszka, Bernd
    Muydinov, Ruslan
    CHEMPHYSCHEM, 2023, 24 (14)
  • [4] Manipulating the Coordination Chemistry of Ru-N(O)-C Moieties for Fast Alkaline Hydrogen Evolution Kinetics
    Lao, Mengmeng
    Zhao, Guoqiang
    Li, Peng
    Ma, Tianyi
    Jiang, Yinzhu
    Pan, Hongge
    Dou, Shi Xue
    Sun, Wenping
    ADVANCED FUNCTIONAL MATERIALS, 2021, 31 (33)
  • [5] Influence of Alkali Metal Cations on the Hydrogen Evolution Reaction Activity of Pt, Ir, Au, and Ag Electrodes in Alkaline Electrolytes
    Xue, Song
    Garlyyev, Batyr
    Watzele, Sebastian
    Liang, Yunchang
    Fichtner, Johannes
    Pohl, Marcus D.
    Bandarenka, Aliaksandr S.
    CHEMELECTROCHEM, 2018, 5 (17): : 2326 - 2329
  • [6] Tuning the electrocatalytic activity of Pt by structurally ordered PdFe/C for the hydrogen oxidation reaction in alkaline media
    Xiao, Weiping
    Lei, Wen
    Wang, Jie
    Gao, Guoying
    Zhao, Tonghui
    Cordeiro, Macro A. L.
    Lin, Ruoqian
    Gong, Mingxing
    Guo, Xuyun
    Stavitski, Eli
    Xin, Huolin L.
    Zhu, Ye
    Wang, Deli
    JOURNAL OF MATERIALS CHEMISTRY A, 2018, 6 (24) : 11346 - 11352
  • [7] Minireview of the Electrocatalytic Local Environment in Alkaline Hydrogen Evolution
    Wang, Xuesi
    Ruan, Qiushi
    Sun, Zhengming
    ENERGY & FUELS, 2023, 37 (23) : 17667 - 17680
  • [8] Engineering of Ru/Ru2P interfaces superior to Pt active sites for catalysis of the alkaline hydrogen evolution reaction
    Liu, Zhao
    Li, Zhe
    Li, Jing
    Xiong, Jie
    Zhou, Shunfa
    Liang, Jiawei
    Cai, Weiwei
    Wang, Chao
    Yang, Zehui
    Cheng, Hansong
    JOURNAL OF MATERIALS CHEMISTRY A, 2019, 7 (10) : 5621 - 5625
  • [9] Theoretical and Experimental Understanding of Hydrogen Evolution Reaction Kinetics in Alkaline Electrolytes with Pt-Based Core-Shell Nanocrystals
    Kim, Jeonghyeon
    Kim, Haesol
    Lee, Won-Jae
    Ruqia, Bibi
    Baik, Hionsuck
    Oh, Hyung-Suk
    Paek, Seung-Min
    Lim, Hyung-Kyu
    Choi, Chang Hyuck
    Choi, Sang-Il
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2019, 141 (45) : 18256 - 18263
  • [10] Asymmetric interfacial engineering regulated charge distribution on Ru/Ni-N-C sites for efficient hydrogen evolution reaction in alkaline and seawater electrolytes
    Yu, Rui
    Cao, Xi
    Zhu, Chengyang
    Chen, Qingqing
    Yan, Ziyi
    Jiang, Binbin
    Mao, Junjie
    Wei, Xianwen
    SCIENCE CHINA-CHEMISTRY, 2025,
12345