Absolute cross sections for dissociative electron attachment to HCCCN

被引:12
作者
Gilmore, T. D. [1 ]
Field, T. A. [1 ]
机构
[1] Queens Univ Belfast, Ctr Plasma Phys, Sch Maths & Phys, Belfast BT7 1NN, Antrim, North Ireland
关键词
dissociative electron attachment; absolute cross sections; HCCCN; cyanoacetylene; propiolonitrile; BEB electron impact ionization cross section; IMPACT IONIZATION; MOLECULES; COLLISIONS; IONS; HC3N;
D O I
10.1088/0953-4075/48/3/035201
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
New absolute cross sections for dissociative electron attachment to HCCCN (cyanoacetylene or propiolonitrile) in the range of 0-10 eV electron energy are presented here, which have been determined from a new analysis of previously reported data (Graupner et al 2006 New J. Phys. 8 117). The highest cross sections are observed for the formation of CN- at 5.3 eV and CCCN- at 5.1 eV; approximately 0.06 angstrom(2) and 0.05 angstrom(2) respectively. As part of the re-analysis, it was necessary to determine absolute cross sections for electron-impact ionization of HCCCN with the binary-encounter Bethe method. These electron-impact ionization absolute cross sections for HCCCN are also presented here; the maximum value was found to be similar to 6.6 angstrom(2) at similar to 80 eV.
引用
收藏
页数:5
相关论文
共 23 条
[1]   EQUILIBRIUM GEOMETRY OF HC3N [J].
BOTSCHWINA, P ;
HORN, M ;
SEEGER, S ;
FLUGGE, J .
MOLECULAR PHYSICS, 1993, 78 (01) :191-198
[2]   Dissociative Electron Attachment to HCN, HCCH and HCCCN [J].
Chourou, S. T. ;
Orel, A. E. .
EIGHTH INTERNATIONAL CONFERENCE ON DISSOCIATIVE RECOMBINATION: THEORY, EXPERIMENTS AND APPLICATIONS (DR2010), 2011, 300
[3]   Dissociative electron attachment to HCN and HNC [J].
Chourou, S. T. ;
Orel, A. E. .
PHYSICAL REVIEW A, 2009, 80 (03)
[4]   Remote observations of the composition of cometary volatiles [J].
Crovisier, J ;
Bockelée-Morvan, D .
SPACE SCIENCE REVIEWS, 1999, 90 (1-2) :19-32
[5]   Experimental observation of dissociative electron attachment to S2O and S2O2 with a new spectrometer for unstable molecules [J].
Field, TA ;
Slattery, AE ;
Adams, DJ ;
Morrison, DD .
JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS, 2005, 38 (03) :255-264
[6]  
Gilmore T D, 2015, DISSOCIATIVE EL UNPB
[7]   Dissociative electron attachment to HCCCN [J].
Graupner, K. ;
Merrigan, T. L. ;
Field, T. A. ;
Youngs, T. G. A. ;
Marr, P. C. .
NEW JOURNAL OF PHYSICS, 2006, 8
[8]  
GRAVES DB, 1996, DATABASE NEEDS MODEL
[9]  
Hotop H, 2003, ADV ATOM MOL OPT PHY, V49, P85
[10]   Cross sections for electron collisions with water molecules [J].
Itikawa, Y ;
Mason, N .
JOURNAL OF PHYSICAL AND CHEMICAL REFERENCE DATA, 2005, 34 (01) :1-22