Hydrothermal synthesis of potassium copper phosphate hydrate and ludjibaite microcrystals

被引：18
|
作者：
Xu, Jiasheng [1 ]
Zhang, Jie [1 ]
Qian, Jianhua [1 ]
机构：
[1] Bohai Univ, Coll Chem & Chem Engn, Jinzhou 121013, Peoples R China
来源：
JOURNAL OF ALLOYS AND COMPOUNDS | 2010年 / 494卷 / 1-2期
关键词：
Potassium copper phosphate hydrate; Ludjibaite; Crystal growth; Chemical synthesis; CRYSTAL-GROWTH; SOLVENT; ORTHOPHOSPHATE; LINDGRENITE;
D O I：
10.1016/j.jallcom.2010.01.022
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A hydrothermal route has been designed for the selective synthesis of potassium copper phosphate hydrate [CuK(PO4)center dot H2O] (PCPH) and ludjibaite [Cu-5(OH)(4)(PO4)(2)] microcrystals. The final products of this hydrothermal process are determined by the reaction media (in an ethanol/water mixed solvent). The ethanol molecule acts as a switch: when ethanol is added (volume ratio of ethanol to water being 3:1), the product is PCPH; when in the absence of ethanol, the product is ludjibaite. These results demonstrated that such a binary reaction media could provide an alternative and versatile strategy for controlling inorganic microcrystals by simply manipulating the supersaturation of the growing solution. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码：319 / 322
页数：4
相关论文
共 50 条
  • [1] Vibrational spectroscopy of the basic copper phosphate minerals: pseudomalachite, ludjibaite and reichenbachite
    Frost, RL
    Kloprogge, T
    Williams, PA
    Martens, W
    Johnson, TE
    Leverett, P
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2002, 58 (13) : 2861 - 2868
  • [2] Understanding the role of precursor concentration in the hydrothermal synthesis of nickel phosphate hydrate for supercapacitors
    Gaikwad, Neha K.
    Patil, Satyajeet S.
    Kulkarni, Abhishek A.
    Dahotre, Rushikesh M.
    Salunkhe, Ankita P.
    Patil, Pramod S.
    Bhat, Tejasvinee S.
    JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2024, 35 (04)
  • [3] Understanding the role of precursor concentration in the hydrothermal synthesis of nickel phosphate hydrate for supercapacitors
    Neha K. Gaikwad
    Satyajeet S. Patil
    Abhishek A. Kulkarni
    Rushikesh M. Dahotre
    Ankita P. Salunkhe
    Pramod S. Patil
    Tejasvinee S. Bhat
    Journal of Materials Science: Materials in Electronics, 2024, 35
  • [4] Raman spectroscopy of the basic copper phosphate minerals cornetite, libethenite, pseudomalachite, reichenbachite and ludjibaite
    Frost, RL
    Williams, PA
    Martens, W
    Kloprogge, JT
    Leverett, P
    JOURNAL OF RAMAN SPECTROSCOPY, 2002, 33 (04) : 260 - 263
  • [5] Synthesis of PbS microcrystals via a hydrothermal process
    Wang, SQ
    Pan, AL
    Yin, HY
    He, YP
    Lei, Y
    Xu, ZD
    Zou, BS
    MATERIALS LETTERS, 2006, 60 (9-10) : 1242 - 1246
  • [6] Hydrothermal synthesis of cubic boron nitride microcrystals
    Lian, Gang
    Zhang, Xiao
    Zhu, Lingling
    Tan, Miao
    Cui, Deling
    Wang, Qilong
    RESEARCH ON CHEMICAL INTERMEDIATES, 2011, 37 (2-5) : 369 - 374
  • [7] Hydrothermal synthesis of cubic boron nitride microcrystals
    Gang Lian
    Xiao Zhang
    Lingling Zhu
    Miao Tan
    Deling Cui
    Qilong Wang
    Research on Chemical Intermediates, 2011, 37 : 369 - 374
  • [8] A microporous potassium vanadyl phosphate analogue of mahnertite: hydrothermal synthesis and crystal structure
    Yakubovich, Olga V.
    Steele, Ian M.
    Kiriukhina, Galina V.
    Dimitrova, Olga V.
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-CRYSTALLINE MATERIALS, 2015, 230 (05): : 337 - 344
  • [9] The basic copper phosphate minerals pseudomalachite, ludjibaite and reichenbachite: an infrared emission and Raman spectroscopic study
    Martens, WN
    Frost, RL
    Williams, PA
    NEUES JAHRBUCH FUR MINERALOGIE-MONATSHEFTE, 2003, (08): : 337 - 362
  • [10] Synthesis, morphological, and ionic conduction studies of a copper potassium phosphate compound
    Ajili, M.
    Gharbi, I
    Oueslati, A.
    IONICS, 2023, 29 (01) : 353 - 361
12345