A theoretical study of the mechanism of oxidative dihydrogen addition to palladium clusters

被引：0
|
作者：
Mamaev, VM [1 ]
Gloriozov, IP [1 ]
Simonyan, VV [1 ]
Zernova, EV [1 ]
Prisyajnyuk, AV [1 ]
Ustynyuk, YA [1 ]
机构：
[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119899, Russia
来源：
MENDELEEV COMMUNICATIONS | 1997年 / 06期
关键词：
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The mechanism of dihydrogen oxidative addition to the simplest palladium cluster has been analysed within the framework of the reaction-path Hamiltonian approximation; a planar dihydride complex has been found to form without the potential energy barrier and intramolecular degenerate exchange of the protons in the complex has been investigated.
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页码：246 / 248
页数：3
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