Products of reaction of tricyclo[4.1.0.02,7]heptane and 1-bromotricyclo[4.1.0.02,7]heptane with hydrogen sulfide, and syntheses based thereon

被引：4
|
作者：
Vasin, VA [1 ]
Kostryukov, SG
Razin, VV
机构：
[1] Mordovian NP Ogarev State Univ, Saransk 430000, Russia
[2] St Petersburg State Univ, St Petersburg 198904, Russia
来源：
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY | 2002年 / 38卷 / 11期
关键词：
D O I：
10.1023/A:1022597614806
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
By reactions of 1-R-tricyclo[4.1.0.0(2,7)]heptanes (R = H, Br) with hydrogen sulfide initiated by UV irradiation endo-6-bicyclo[3.1.1]heptanethiols and bis(endo-6-bicyclo[3.1.1]heptyl) sulfides were synthesized. The sulfides were oxidized to the corresponding sulfoxides and sulfones. The results of HBr elimination from the bromine-substituted sulfoxides and sulfones effected by potassium tert-butylate are discussed. The latter reaction results in the recovery of the system of I-substituted tricyclo[4.1.0.0(2,7)]heptane.
引用
收藏
页码：1582 / 1587
页数：6
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