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Chiral recognition with a benzofuran receptor that mimics an oxyanion hole
被引:13
|作者:
Fuentes de Arriba, Angel L.
[1
]
Gomez Herrero, Angel
[1
]
Rubio, Omayra H.
[1
]
Monleon, Laura M.
[1
]
Simon Rubio, Luis
[1
]
Alcazar, Victoria
[2
]
Sanz, Francisca
[3
]
Moran, Joaquin R.
[1
]
机构:
[1] Univ Salamanca, Dept Organ Chem, E-37008 Salamanca, Spain
[2] Tech Univ Madrid, Ind Chem & Environm Engn Dept, Madrid 28006, Spain
[3] Univ Salamanca, Xray Diffract Serv, E-37008 Salamanca, Spain
关键词:
NUCLEOPHILIC-ADDITION;
ARTIFICIAL ENZYMES;
ACID RECEPTORS;
CATALYSIS;
PYRROLIDINE;
DESIGN;
D O I:
10.1039/c4ob01954g
中图分类号:
O62 [有机化学];
学科分类号:
070303 ;
081704 ;
摘要:
A new chiral benzofuran receptor has been synthesized and its properties in the association of amino acid derivatives have been studied. X-ray structures were obtained and these corroborate the presence of an oxyanion-hole motif in these structures.
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页码:493 / 501
页数:9
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