Synthesis, structural characterization, catalytic activity on aerobic oxidation of novel Co(II) and Fe(II) phthalocyanines and computational studies of 4-[2-(2,3-dichlorophenoxy)ethoxy]phthalonitrile

被引：28

作者：

Saka, Ece Tugba ^{[1
]}

Uzun, Serap ^{[2
]}

Caglar, Yasemin ^{[3
]}

机构：

[1] Karadeniz Tech Univ, Fac Sci, Dept Chem, TR-61080 Trabzon, Turkey

[2] Giresun Univ, Fac Engn, Dept Elect & Elect Engn, TR-28200 Giresun, Turkey

[3] Giresun Univ, Fac Engn, Dept Bioengn, TR-28200 Giresun, Turkey

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2016年 / 810卷

关键词：

Phthalocyanine; Phthalonitrile; Iron; Cobalt; Phenolic compounds; Oxidation; METAL-FREE; COBALT PHTHALOCYANINE; WATER; ELECTROCHEMISTRY; 2,6-DI-TERT-BUTYLPHENOL; 2,4,6-TRICHLOROPHENOL; HYPERPOLARIZABILITY; TETRASULFONATES; AUTOXIDATION; SOLVENT;

D O I：

10.1016/j.jorganchem.2016.03.005

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

4-[2-(2,3-dichlorophenoxy)ethoxy] substituted Co(II) and Fe(II) phthalocyanines were successfully synthesized and characterized by the spectroscopic methods (IR, H-1 NMR, UV-Vis, mass spectrometry and elemental analysis). Determination of the optimal conditions for oxidation of phenolic compounds, the catalytic reactions were carried out change the reaction temperature, time and different oxidants, subst./cat. ratio. In the presence of phthalocyanine derivatives 4 and 5, we demonstrated that phenolic compounds oxidize to the less harmfull products with high conversion and yield. Additionally, the computational studies of 4-[2-(2,3-dichlorophenoxy) ethoxy]phthalonitrile were done in this work. (C) 2016 Elsevier B.V. All rights reserved.

引用

页码：25 / 32

页数：8

共 27 条

[1] Co(II) and Fe(II) phthalocyanines: Synthesis, characterization and catalytic activity on cyclohexene oxidation with different oxygen source
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[2] SYNTHESIS, MOLECULAR STRUCTURE AND SPECTROSCOPIC AND COMPUTATIONAL STUDIES ON 4-(2-(2-(2-FORMYLPHENOXY)ETHOXY)ETHOXY)PHTHALONITRILE AS A FUNCTIONALIZED PHTHALONITRILE
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[3] New soluble peripherally tetra-substituted Co(II), Fe(II) phthalocyanines: Synthesis, spectroscopic characterization and their catalytic activity in cyclohexene oxidation
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[5] Peripherally tetra-{2-(2,3,5,6-tetrafluorophenoxy)ethoxy} substituted cobalt(II), iron(II) metallophthalocyanines: Synthesis and their electrochemical, catalytic activity studies
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[6] Synthesis, electrochemistry of metal-free, copper, titanium phthalocyanines and investigation of catalytic activity of cobalt, iron phthalocyanines on benzyl alcohol oxidation bearing 4-{2-[3-trifluoromethyl)phenoxy]ethoxy} groups
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[7] Peripherally and non-peripherally electropolymerizable (2-{2-[4-(1H-pyrrol-1-yl)phenoxy]ethoxy}ethoxy) group substituted cobalt(II), manganese(III) phthalocyanines: Synthesis and electrochemistry
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[8] Fe(II) and Co(II) Complexes of (4-(4-bromophenyl)-[2,2′-bipyridine]-6-carboxylic acid) Synthesis, Characterization and Electrochromic studies
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[9] Synthesis and characterization of novel 4-nitro-2-(octyloxy)phenoxy substituted symmetrical and unsymmetrical Zn(II), Co(II) and Lu(III) phthalocyanines
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[10] Tetra- and octa-[4-(2-hydroxyethyl)phenoxy bearing novel metal-free and zinc(II) phthalocyanines: Synthesis, characterization and investigation of photophysicochemical properties
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