Synthesis, Characterization and Thermal Studies of Poly(4-Vinylpyridine) Composites of Rare Earth Metals

被引:3
|
作者
Khan, Abida Kalsoom [1 ]
Rashid, Rehana [1 ]
Hussain, Majid [1 ]
Yunus, Uzma [2 ]
Akhtar, Zareen [3 ]
Ali, Saqib [3 ]
Zahra, Atiya [1 ]
Mir, Sadullah [1 ]
Ansari, Muhammad Tayyab [4 ]
Mehmood, Zahid [6 ]
Sajjad, Ashif [6 ]
Murtaza, Ghulam [5 ]
机构
[1] COMSATS Inst Informat Technol, Dept Chem, Abbottabad, Pakistan
[2] Allama Iqbal Open Univ, Dept Chem, Islamabad, Pakistan
[3] Quaid I Azam Univ, Dept Chem, Islamabad, Pakistan
[4] Bahauddin Zakariya Univ, Fac Pharm, Multan, Pakistan
[5] COMSATS Inst Informat Technol, Dept Pharm, Abbottabad, Pakistan
[6] Univ Baluchistan, Inst Biochem, Quetta, Pakistan
关键词
Poly(4-vinylpyridine); Rare earth metals salts; Thermal stability; Polymer metal composite; COMPLEXES; BEHAVIOR;
D O I
10.1007/s13369-015-1592-2
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Sol-gel method has been adapted to synthesize the composites of poly(4-vinylpyridine) with different rare earth inorganic metal salts. These salts have been incorporated into polymer for enhancing the thermal stability. The resulting products were characterized through Fourier Transform Infrared Spectroscopy, X-ray diffractometry (XRD), and thermogravimetric analysis. The XRD data show that amorphous character of polymer is enhanced by incorporating inorganic metal salts. Thermal degradation data depict thermal stability of the synthesized composites. Additionally, thermal degradation data depict that thermal stability of synthesized composites is enhanced and are more thermal stable than P4VP itself, which makes them suitable for coatings.
引用
收藏
页码:105 / 109
页数:5
相关论文
共 50 条
  • [41] Preparation and thermal characterization of poly(2-vinylpyridine) copolymers coordinated to Cr nanoparticles
    Lekesiz, Tugba Orhan
    Kayran, Ceyhan
    Hacaloglu, Jale
    POLYMERS FOR ADVANCED TECHNOLOGIES, 2015, 26 (06) : 555 - 560
  • [42] Synthesis, characterization, spectroscopy and thermal analysis of rare earth picrate complexes with L-leucine
    T. S. Martins
    J. R. Matos
    G. Vicentini
    P. C. Isolani
    Journal of Thermal Analysis and Calorimetry, 2006, 86 : 351 - 357
  • [43] Synthesis of Polystyrene and Poly(4-vinylpyridine) Mixed Grafted Silica Nanoparticles via a Combination of ATRP and CuI-Catalyzed Azide-Alkyne Click Chemistry
    Wu, Lei
    Glebe, Ulrich
    Boeker, Alexander
    MACROMOLECULAR RAPID COMMUNICATIONS, 2017, 38 (01)
  • [44] Synthesis, characterization, spectroscopy and thermal analysis of rare earth picrate complexes with L-leucine
    Martins, T. S.
    Matos, J. R.
    Vicentini, G.
    Isolani, P. C.
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2006, 86 (02) : 351 - 357
  • [45] 2-Methoxyethylamino-bis(phenolate)yttrium Catalysts for the Synthesis of Highly Isotactic Poly(2-vinylpyridine) by Rare-Earth Metal-Mediated Group Transfer Polymerization
    Kronast, Alexander
    Reiter, Dominik
    Altenbuchner, Peter T.
    Vagin, Sergei I.
    Rieger, Bernhard
    MACROMOLECULES, 2016, 49 (17) : 6260 - 6267
  • [46] The Influence of Magnesium Acetate on the Structure Formation of Polystyrene-block-poly(4-vinylpyridine)-Based Integral-Asymmetric Membranes
    Gallei, Markus
    Rangou, Sofia
    Filiz, Volkan
    Buhr, Kristian
    Bolmer, Sabrina
    Abetz, Clarissa
    Abetz, Volker
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 2013, 214 (09) : 1037 - 1046
  • [47] Tetranuclear and Pentanuclear Compounds of the Rare-Earth Metals: Synthesis and Magnetism
    Yadav, Munendra
    Mondal, Abhishake
    Mereacre, Valeriu
    Jana, Salil Kumar
    Powell, Annie K.
    Roesky, Peter W.
    INORGANIC CHEMISTRY, 2015, 54 (16) : 7846 - 7856
  • [48] Optimization of the carrier recombination and transmission properties in perovskite LEDs by doping poly (4-vinylpyridine) and graphene quantum dots made of chitin
    Yan, Zhen-Li
    Liang, Fang-Cheng
    Yeh, Chia-Yu
    Kurniawan, Darwin
    Benas, Jean-Sebastien
    Chen, Wei-Cheng
    Cho, Chia-Jung
    Chiang, Wei-Hung
    Jeng, Ru-Jong
    Kuo, Chi-Ching
    CHEMICAL ENGINEERING JOURNAL, 2022, 444
  • [49] Synthesis, characterization and photophysical studies of rare earth metal complexes with a mesogenic Schiff-base
    Yerrasani, Rajasekhar
    Karunakar, M.
    Dubey, Ragini
    Singh, Angad Kumar
    Nandi, Rajib
    Singh, Ranjan K.
    Rao, T. R.
    JOURNAL OF MOLECULAR LIQUIDS, 2016, 216 : 510 - 515
  • [50] Amination of Aryl Halides With Aqueous Ammonia Catalyzed by Green Recyclable Poly(4-vinylpyridine)-supported Copper Iodide Nanoparticles Catalyst
    Albadi, Jalal
    Shiran, Jafar Abbasi
    Mansournezhad, Azam
    ACTA CHIMICA SLOVENICA, 2014, 61 (04) : 900 - 903