Semiconductive 1D nanobelt iodoplumbate hybrid with high humidity response

被引：12

作者：

Cai, MinLan ^{[1
,2
]}

Wang, Guan-E ^{[1
]}

Yao, MingShui ^{[1
]}

Wu, GuoDong ^{[1
]}

Li, Ying ^{[3
]}

Xu, Gang ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

[2] Fujian Normal Univ, Coll Chem & Mat Sci, Fujian Key Lab Polymer Mat, Fuzhou 350007, Fujian, Peoples R China

[3] SINOPEC R Res Inst Safety Engn, State Key Lab Safety & Control Chem, Qingdao 266101, Shandong, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2018年 / 93卷

关键词：

Functional motifs; Inorganic-organic hybrid; Nanobelt; Semiconductor; Sensor; INORGANIC-ORGANIC HYBRID; CRYSTAL-STRUCTURES; PHOTOCATALYTIC PROPERTIES; OPTICAL-PROPERTIES; PHASE-TRANSITIONS; PEROVSKITE SHEETS; HIGH-SENSITIVITY; LIGHT EMISSION; LEAD HALIDES; CATIONS;

D O I：

10.1016/j.inoche.2018.05.002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Owing to the structural diversity and potential applications in optoelectronic devices, inorganic-organic hybrid materials have attracted extensive attentions in recent years. They are widely used in the fields of fluorescence, photoconductivity, ferroelectricity and solar cells. A new compound, ((Et-2)HDABH(Et-2)](2)Pb5I14 center dot 2H(2)O (DAB = benzidine), was solvothermally synthesized using [(Et-2)HDABH(Et-2)](2+) as templates and balance cations. The structure is consisted of one-dimensional (1D) nanobelt iodoplumbate, [(Et-2)HDABH(Et-2)](2+) dications and water molecules. The compound exhibits typical semiconductive behaviors, whose conductivity increases along with the raising of temperature. The compound also shows high electrical response to humidity, which indicates great potential application in humidity quantitatively detecting.

引用

页码：42 / 46

页数：5

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