Bis-macromonomers of 2-alkyl-2-oxazolines - synthesis and polymerization

被引：45

作者：

Christova, D ^{[1
]}

Velichkova, R

Goethals, EJ

机构：

[1] Bulgarian Acad Sci, Inst Polymers, BU-1113 Sofia, Bulgaria

[2] State Univ Ghent, Dept Organ Chem, Div Polymer Chem, B-9000 Ghent, Belgium

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 1997年 / 18卷 / 12期

关键词：

D O I：

10.1002/marc.1997.030181210

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Poly(2-alkyl-2-oxazoline)s having an acrylate group at both chain ends were synthesized by terminating living bifunctional poly(2-methyl-2-oxazoline) or poly(2-ethyl-2-oxazoline) with acrylic acid. These macromonomers have been polymerized to the corresponding polyoxazoline networks. Thermal as well as UV-initiated free radical polymerization were applied and the influence of the polymerization conditions and molecular weight of the prepolymer used on the properties of the networks were investigated. Both methods of polymerization produced high fractions of soluble material, probably due to the low concentration of the acrylate end groups.

引用

页码：1067 / 1073

页数：7

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