Synthesis of stable metal-containing porous organic polymers for gas storage

被引：53
|
作者：
Li, Gen [1 ,2 ]
Liu, Qingquan [1 ,2 ,3 ]
Xia, Bijiang [1 ,2 ]
Huang, Jing [1 ,2 ]
Li, Sizhe [1 ,2 ]
Guan, Yuze [1 ,2 ]
Zhou, Hu [1 ,2 ]
Liao, Bo [1 ,2 ]
Zhou, Zhihua [1 ,2 ]
Liu, Bin [3 ]
机构：
[1] Hunan Univ Sci & Technol, Inst Mat Sci & Engn, Xiangtan 411201, Peoples R China
[2] Hunan Prov Key Lab Controllable Preparat & Funct, Xiangtan 411201, Peoples R China
[3] Natl Univ Singapore, Dept Chem & Biomol Engn, Singapore 117585, Singapore
来源：
EUROPEAN POLYMER JOURNAL | 2017年 / 91卷
基金：
中国国家自然科学基金;
关键词：
High BET surface areas; Porous polymers; CO2; capture; CONJUGATED MICROPOROUS POLYMERS; COPOLYMER NETWORKS; HYDROGEN SORPTION; LINKED POLYMERS; SURFACE-AREA; LOW-PRESSURE; FRAMEWORKS; CO2; ADSORPTION; FERROCENE;
D O I：
10.1016/j.eurpolymj.2017.03.014
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Stable metal-containing porous organic polymers were prepared by condensation reactions between 1,1'-ferrocenedicarboxaldehyde and meso-diamines to form the imine linkages. Gas adsorption test showed that the obtained polymers exhibited BET surface areas in the range of 715-1050 m(2) g(-1), with CO2 adsorption capabilities of 14.8% at 273 K/1 bar. This approach represents a new and effective strategy for the preparation of stable metal-containing porous organic polymers.
引用
收藏
页码：242 / 247
页数：6
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