Synthesis of stable metal-containing porous organic polymers for gas storage

被引：53

作者：

Li, Gen ^{[1
,2
]}

Liu, Qingquan ^{[1
,2
,3
]}

Xia, Bijiang ^{[1
,2
]}

Huang, Jing ^{[1
,2
]}

Li, Sizhe ^{[1
,2
]}

Guan, Yuze ^{[1
,2
]}

Zhou, Hu ^{[1
,2
]}

Liao, Bo ^{[1
,2
]}

Zhou, Zhihua ^{[1
,2
]}

Liu, Bin ^{[3
]}

机构：

[1] Hunan Univ Sci & Technol, Inst Mat Sci & Engn, Xiangtan 411201, Peoples R China

[2] Hunan Prov Key Lab Controllable Preparat & Funct, Xiangtan 411201, Peoples R China

[3] Natl Univ Singapore, Dept Chem & Biomol Engn, Singapore 117585, Singapore

来源：

EUROPEAN POLYMER JOURNAL | 2017年 / 91卷

基金：

中国国家自然科学基金;

关键词：

High BET surface areas; Porous polymers; CO2; capture; CONJUGATED MICROPOROUS POLYMERS; COPOLYMER NETWORKS; HYDROGEN SORPTION; LINKED POLYMERS; SURFACE-AREA; LOW-PRESSURE; FRAMEWORKS; CO2; ADSORPTION; FERROCENE;

D O I：

10.1016/j.eurpolymj.2017.03.014

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Stable metal-containing porous organic polymers were prepared by condensation reactions between 1,1'-ferrocenedicarboxaldehyde and meso-diamines to form the imine linkages. Gas adsorption test showed that the obtained polymers exhibited BET surface areas in the range of 715-1050 m(2) g(-1), with CO2 adsorption capabilities of 14.8% at 273 K/1 bar. This approach represents a new and effective strategy for the preparation of stable metal-containing porous organic polymers.

引用

页码：242 / 247

页数：6

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