Anchoring SbxOy/SnO2 nano-heterojunction on reduced graphene oxide as lithium ion batteries anodes with remarkable rate performance and excellent cycle stability

被引:3
|
作者
Zhang, Bin [1 ]
Zhang, Chun [1 ]
Liu, Baoyong [1 ]
Zhou, Xiaozhong [2 ]
Huang, Guowei [3 ]
机构
[1] Lanzhou Jiaotong Univ, Sch Chem & Chem Engn, Lanzhou 730070, Peoples R China
[2] Northwest Normal Univ, Coll Chem & Chem Engn, Key Lab EcoEnvironm Related Polymer Mat, Key Lab Gansu Polymer Mat, Lanzhou 730070, Peoples R China
[3] Lanzhou Univ Technol, State Key Lab Adv Proc & Recycling Nonferrous Met, Lanzhou 730050, Peoples R China
关键词
Nano-heterojunction; SbxOy; SnO2; Reduced graphene oxide (rGO); Rate performance; Lithium ion batteries; SNS/SNO2; HETEROSTRUCTURES; REVERSIBLE LITHIUM; SODIUM; CARBON; SNO2; NANOPARTICLES; COMPOSITE; SHEETS; NETWORK;
D O I
10.1007/s11581-021-04200-z
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Constructing the nanometer heterojunction can enhance the surface reaction kinetics and promote the transmission of charge because of internal micro-electric fields of heterogeneous interfaces. Herein, SbxOy/SnO2 nano-heterostructures anchored on the surface of reduced graphene oxide (SbxOy/SnO2/rGO) were prepared by a simple one-step solvothermal method. The SbxOy/SnO2/rGO used as anode for lithium ion batteries possesses remarkable rate performance, high discharge, and charge specific capacities of 518.6 and 515.3 mA h g(-1) after 1000 cycles at 4000 mA g(-1), respectively, as well as excellent cycle stability (the capacity loss rate per cycle is only 0.00379%). The excellent electrochemical properties of the SbxOy/SnO2/rGO material can be attributed to the successful builds of nano-heterostructures.
引用
收藏
页码:4205 / 4216
页数:12
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