Enantioselective hydrogenation of acetophenone by (1S, 2S)-DPEN-Ru(II)Cl2(PPh3)2 encapsulated in Al-MCM-41

被引：3

作者：

Liu, Jian Hong ^{[1
,2
,3
]}

Liang, Dong ^{[1
]}

Fan, Bin Bin ^{[1
]}

Li, Rui Feng ^{[1
]}

Chen, Hua ^{[3
]}

机构：

[1] Taiyuan Univ Technol, Key Lab Coal Sci & Technol, MOE, Inst Special Chem, Taiyuan 030024, Peoples R China

[2] Shanxi Datong Univ, Coll Chem & Chem Engn, Datong 037009, Peoples R China

[3] Sichuan Univ, Key Lab Green Chem & Technol, MOE, Inst Homogeneous Catalysis,Coll Chem, Chengdu 610064, Peoples R China

来源：

CHINESE CHEMICAL LETTERS | 2010年 / 21卷 / 07期

关键词：

Encapsulation; Al-MCM-41; Heterogeneous enantioselective hydrogenation; Acetophenone; S; S-DPEN-Ru-Al-MCM-Si; ASYMMETRIC HYDROGENATION; AROMATIC KETONES; CATALYSTS; RU; COMPLEXES; LIQUID;

D O I：

10.1016/j.cclet.2010.03.011

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A chiral ruthenium complex [(1S, 2S)-DPEN]-RuCl2(PPh3), (DPEN = 1,2-diphenylethylenediamine, PPh3 = triphenylphosphine) was encapsulated in the channel of Al-MCM-41 by electrostatic adsorption and 1,1-dichlorosilacyclobutane modification. The prepared heterogeneous catalyst showed the same catalytic activity and enantioselectivity as the corresponding homogeneous catalyst in the asymmetric hydrogenation of acetophenone, and could be reused at least seven times without significant loss of catalytic activity and enantioselectivity. (C) 2010 Rui Feng Li. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.

引用

页码：802 / 806

页数：5

共 22 条

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