A distorted square-planar PdII complex with a shortened Pd-Cl bond induced by the bulky terpyridyl ligand 6,6"-di-mesityl-2,2′:6′,2"-terpyridine

被引：6

作者：

Onoda, A ^{[1
]}

Kawakita, K ^{[1
]}

Okamura, T ^{[1
]}

Yamamoto, H ^{[1
]}

Ueyama, N ^{[1
]}

机构：

[1] Osaka Univ, Grad Sch Sci, Dept Macromol Sci, Osaka 5600043, Japan

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2003年 / 59卷

关键词：

D O I：

10.1107/S1600536803008626

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title complex, chloro(6,6"-dimesityl-2,2':6',2"-terpyridine) palladium(II) tetrachloropalladium(II) dichloromethane tetrasolvate, [(PdCl)-Cl-II(dmtpy)](2)[(PdCl4)-Cl-II].4CH(2)Cl(2) (dmtpy is 6,6"-dimesityl-2,2':6',2"-terpyridine, C33H31N3), was synthesized and the crystal structure of the dichloromethane tetrasolvate has been determined. The complex has a distorted square-planar coordination formed by three N atoms and a chloride ion, the distortion caused by the extremely bulky substituted terpyridyl ligand.

引用

页码：M291 / M293

页数：3

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