Modeling experimental oscillations in liquid membranes with delay equations

被引:27
作者
Srividhya, J [1 ]
Gopinathan, MS [1 ]
机构
[1] Indian Inst Technol, Dept Chem, Madras 600036, Tamil Nadu, India
关键词
D O I
10.1021/jp021240z
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The oil/water interface has been of great importance in understanding the dynamics of oscillatory interfacial mass transfer phenomenon and other bio-oscillations in excitable membranes. The oscillatory mass transfer across the oil/water interface generates an oscillating interfacial potential, which is measurable with suitable experimental setup. A detailed and systematic experimental study on the CTAB/picric acid system is done and a diffusion model is studied using delay-differential equations. It is found that a two-variable model with delay in one of the variables is able to explain the observed phenomenon satisfactorily.
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页码:1438 / 1443
页数:6
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