Asymmetric catalysis of carbonyl-ene and aldol reactions with fluoral by chiral binaphthol-derived titanium complex

被引：84
|
作者：
Mikami, K
Yajima, T
Takasaki, T
Matsukawa, S
Terada, M
Uchimaru, T
Maruta, M
机构：
[1] MINIST INT TRADE & IND,AIST,NATL INST MAT & CHEM RES,TSUKUBA,IBARAKI 305,JAPAN
[2] CENT GLASS CO LTD,TOKYO RES CTR,KAWAGOE,SAITAMA 35011,JAPAN
来源：
TETRAHEDRON | 1996年 / 52卷 / 01期
关键词：
D O I：
10.1016/0040-4020(95)00862-3
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The chiral titanium complex-catalyzed ene-type reaction and the Mukaiyama aldol reaction with fluoral are shown to serve as an efficient route to the enantioselective and diastereoselective synthesis of CF3-substituted components of biological and synthetic importance.
引用
收藏
页码：85 / 98
页数：14
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